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Stoichiometry & Chemical Reactions

Law of Reciprocal Proportions

The principle that the mass ratios in which two elements combine with a third are related by a simple ratio to the ratio in which they combine with each other.

Unit Dimensionless

In depth

Proposed by Richter, the law was further evidence that each element has a fixed combining capacity, and it underpins the concept of equivalent weight. It follows naturally from atomic theory, since each element combines in whole numbers of atoms whatever its partner.

Examples in the real world

Hydrogen and carbon combine with oxygen in ratios that predict correctly the 1:3 H:C mass ratio in methane.