Terms starting with I
53 terms · page 2 of 3
Ionic Bond
Chemical Bonding & Molecular Structure
kJ/mol
The electrostatic attraction between oppositely charged ions formed by the complete transfer of electrons from one atom to another.
F ∝ q₁q₂ / r²
Ionic Equilibrium
Chemical Equilibrium
mol/L
An equilibrium involving ions in solution, such as the dissociation of weak electrolytes or the dissolution of sparingly soluble salts.
Ionic Product
Chemical Equilibrium
Various
The product of the ion concentrations actually present in a solution, each raised to its stoichiometric power.
Q_sp = [A⁺]^m[B⁻]^n
Ionic Product of Water
Acids, Bases & Salts
mol²/L²
The equilibrium constant for the self-ionisation of water, equal to the product of the hydrogen and hydroxide ion concentrations.
Kw = [H⁺][OH⁻] = 1.0 × 10⁻¹⁴
Ionic Radius
Atomic Structure & Periodicity
pm
The effective radius of an ion within a crystal lattice, deduced from measured interionic distances.
Ionic Strength
Chemical Equilibrium
mol/L
A measure of the total concentration of ionic charge in a solution.
I = ½ Σ c_i z_i²
Ionisation Energy
Atomic Structure & Periodicity
kJ/mol
The minimum energy needed to remove the most loosely held electron from one mole of gaseous atoms in their ground state.
X(g) → X⁺(g) + e⁻
Ionisation Isomerism
Inorganic & Coordination Chemistry
Dimensionless
Isomerism arising when an anion inside the coordination sphere exchanges places with the counter ion outside it.
Ionising Radiation
Nuclear & Radiochemistry
eV
Radiation with enough energy to remove electrons from atoms, creating ions.
Ion–Dipole Interaction
Chemical Bonding & Molecular Structure
kJ/mol
The attraction between an ion and the oppositely charged end of a polar molecule.
E ∝ q μ / r²
Irreversible Process
Thermochemistry & Thermodynamics
J/K
A real process that passes through non-equilibrium states and cannot be reversed without leaving a permanent change in the surroundings.
ΔS_universe > 0
Irreversible Reaction
Stoichiometry & Chemical Reactions
Dimensionless
A reaction that proceeds essentially to completion, with negligible conversion back to reactants.
A + B → C
Isobar
Atomic Structure & Periodicity
Dimensionless
One of a set of atoms of different elements that share the same mass number but have different atomic numbers.
same A, different Z
Isobaric Process
Thermochemistry & Thermodynamics
J
A process carried out at constant pressure.
q_p = ΔH
Isochoric Process
Thermochemistry & Thermodynamics
J
A process carried out at constant volume, so that no expansion work is done.
w = 0, q_V = ΔU
Isoelectric Point
Biochemistry & Polymer Chemistry
Dimensionless
The pH at which a molecule carries no net electrical charge.
pI = (pKa₁ + pKa₂)/2
Isoelectronic Species
Atomic Structure & Periodicity
Dimensionless
Atoms or ions that possess the same number of electrons and the same electron configuration.
Isolated System
Thermochemistry & Thermodynamics
Dimensionless
A system that exchanges neither energy nor matter with its surroundings.
ΔU = 0
Isomerism
Organic Chemistry
Dimensionless
The existence of two or more compounds with the same molecular formula but different arrangements of atoms.
Isomerism in Coordination Compounds
Inorganic & Coordination Chemistry
Dimensionless
The existence of complexes with the same formula but different structures or spatial arrangements.
Isomorphism
States of Matter & Gas Laws
Dimensionless
The property of two or more different substances crystallising in the same structural form.
Isothermal Process
Thermochemistry & Thermodynamics
J
A process carried out at constant temperature, with heat exchanged as needed to maintain it.
ΔU = 0 (ideal gas), w = −nRT ln(V₂/V₁)
Isotone
Atomic Structure & Periodicity
Dimensionless
One of a set of nuclides that contain the same number of neutrons but different numbers of protons.
same N, different Z
Isotonic Solution
Solutions & Colligative Properties
atm
A solution having the same osmotic pressure as another, so that no net osmotic flow occurs between them.
π₁ = π₂