Home Wikituition Browse all terms Categories
Random term
Thermochemistry & Thermodynamics

Enthalpy of Fusion

The enthalpy change when one mole of a solid melts to a liquid at its melting point.

Formula / equation ΔH_fus
Unit kJ/mol

In depth

Melting only needs to loosen the lattice enough for particles to move past one another, not to separate them entirely, so fusion enthalpy is far smaller than vaporisation enthalpy. Its magnitude reflects the strength of the forces holding the lattice together.

Examples in the real world

Ice needs 6.01 kJ/mol, sodium chloride 28.2 kJ/mol, and tungsten 52.3 kJ/mol.