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Results for “Catalyst”

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Chemical Kinetics & Catalysis

Catalyst

A substance that increases the rate of a reaction by providing an alternative pathway of lower activation energy, without being consumed.

Dimensionless
Chemical Kinetics & Catalysis

Catalyst Poisoning

The loss of catalytic activity caused by a substance binding irreversibly to the active sites.

Dimensionless
Chemical Equilibrium

Effect of a Catalyst on Equilibrium

A catalyst changes how quickly equilibrium is reached but never where that equilibrium lies.

K unchanged Dimensionless
Chemical Kinetics & Catalysis

Active Site

The specific region of a catalyst or enzyme at which the reacting molecules bind and are transformed.

Dimensionless
Chemical Kinetics & Catalysis

Catalysis

The process by which a reaction rate is increased through the action of a catalyst.

Dimensionless
Biochemistry & Polymer Chemistry

Enzyme

A biological catalyst, almost always a protein, that accelerates a specific biochemical reaction.

Dimensionless
Organic Chemistry

Friedel–Crafts Reaction

The introduction of an alkyl or acyl group onto an aromatic ring using a Lewis acid catalyst.

ArH + RCl + AlCl₃ → ArR + HCl Dimensionless
Chemical Kinetics & Catalysis

Heterogeneous Catalysis

Catalysis in which the catalyst is in a different phase from the reactants, usually a solid with gaseous or liquid reagents.

Dimensionless
Chemical Kinetics & Catalysis

Homogeneous Catalysis

Catalysis in which the catalyst is in the same phase as the reactants.

Dimensionless
Chemical Equilibrium

Optimum Conditions for Industrial Yield

The compromise set of temperature, pressure and catalyst chosen to balance equilibrium yield against reaction rate and cost.

Various
Chemical Kinetics & Catalysis

Promoter

A substance that has little catalytic activity itself but greatly increases the effectiveness of a catalyst.

Dimensionless
Chemical Kinetics & Catalysis

Selectivity

The ability of a catalyst to direct a reaction towards one particular product among several possible ones.

selectivity = desired product / total product Dimensionless
Chemical Kinetics & Catalysis

Activation Energy

The minimum energy that colliding particles must possess for a reaction to occur.

Ea = E(transition state) − E(reactants) kJ/mol
Biochemistry & Polymer Chemistry

Addition Polymerisation

Polymerisation in which unsaturated monomers add to one another with no loss of any atoms.

n CH₂=CH₂ → –(CH₂–CH₂)ₙ– Dimensionless
Stoichiometry & Chemical Reactions

Chemical Equation

A symbolic representation of a chemical reaction showing reactants on the left and products on the right.

aA + bB → cC + dD Dimensionless
Chemical Kinetics & Catalysis

Chemical Kinetics

The study of reaction rates, the factors that influence them, and the step-by-step mechanisms by which reactions occur.

mol/(L·s)
Chemical Kinetics & Catalysis

Effective Collision

A collision that actually leads to reaction because it has both sufficient energy and correct orientation.

Dimensionless
Biochemistry & Polymer Chemistry

Enzyme Specificity

The ability of an enzyme to select one substrate, or one class of substrate, and catalyse one particular reaction.

Dimensionless
Chemical Equilibrium

Equilibrium Constant

The fixed ratio of product to reactant terms, each raised to its stoichiometric power, that characterises a reaction at a given temperature.

K = Π[products]^ν / Π[reactants]^ν Various
Chemical Equilibrium

Equilibrium Yield

The proportion of reactant converted to product once equilibrium has been reached.

yield = n_product / n_theoretical Dimensionless
Stoichiometry & Chemical Reactions

Esterification

The acid-catalysed condensation of a carboxylic acid with an alcohol to form an ester and water.

RCOOH + R′OH ⇌ RCOOR′ + H₂O Dimensionless
Electrochemistry & Redox

Fuel Cell

An electrochemical cell that generates electricity continuously from a fuel and oxidant supplied from outside.

V
Electrochemistry & Redox

Hydrogen–Oxygen Fuel Cell

A fuel cell in which hydrogen is oxidised at the anode and oxygen reduced at the cathode, producing only water.

2H₂ + O₂ → 2H₂O, E° = 1.23 V V
Nuclear & Radiochemistry

Nuclear Chemistry

The study of changes that occur in atomic nuclei and of the properties of radioactive substances.

Dimensionless