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Results for “Mole”

256 terms · page 7 of 11


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Solutions & Colligative Properties

Abnormal Molar Mass

A molar mass value obtained from colligative measurements that differs from the true value because the solute associates or dissociates.

M_normal = i × M_observed g/mol
Organic Chemistry

Aldol Condensation

The base-catalysed reaction of two carbonyl compounds to give a beta-hydroxy carbonyl, which often dehydrates to an enone.

2RCH₂CHO → RCH₂CH(OH)CHRCHO Dimensionless
Acids, Bases & Salts

Amphoteric Substance

A substance able to react as either an acid or a base depending on what it meets.

Dimensionless
Chemical Equilibrium

Association Constant

The equilibrium constant for the combination of two species into a single associated entity, the reciprocal of the dissociation constant.

Ka = 1 / Kd L/mol
Foundations of Chemistry

Atomic Mass Unit

A mass unit defined as exactly one twelfth the mass of a free, unbound carbon-12 atom in its ground state.

1 u = 1.66053907 × 10⁻²⁷ kg u (Da)
Atomic Structure & Periodicity

Atomic Orbital

A mathematical function describing the region around a nucleus where an electron of given energy is most likely to be found.

|ψ|² = probability density Dimensionless
States of Matter & Gas Laws

Average Kinetic Energy

The mean translational kinetic energy of the particles in a sample, dependent only on absolute temperature.

KE = (3/2)kT per molecule J
Analytical Chemistry & Spectroscopy

Base Peak

The most intense peak in a mass spectrum, assigned an arbitrary relative abundance of 100%.

Dimensionless
Biochemistry & Polymer Chemistry

Biochemistry

The study of the chemical substances and processes that occur within living organisms.

Dimensionless
States of Matter & Gas Laws

Boiling Point

The temperature at which the vapour pressure of a liquid equals the external pressure acting on it.

p_vap = p_external °C
Chemical Bonding & Molecular Structure

Bonding Pair

A pair of electrons shared between two atoms and responsible for holding them together.

Dimensionless
States of Matter & Gas Laws

Boyle's Law

At constant temperature, the volume of a fixed mass of gas is inversely proportional to its pressure.

p₁V₁ = p₂V₂ Pa·m³
Thermochemistry & Thermodynamics

Calorific Value

The heat released by the complete combustion of unit mass of a fuel.

CV = ΔH_c / molar mass kJ/g
Organic Chemistry

Cannizzaro Reaction

The disproportionation of an aldehyde with no alpha hydrogen under concentrated alkali into an alcohol and a carboxylate.

2RCHO + OH⁻ → RCH₂OH + RCOO⁻ Dimensionless
Organic Chemistry

Chain Isomerism

Structural isomerism arising from different arrangements of the carbon skeleton.

Dimensionless
Chemical Kinetics & Catalysis

Chain Reaction

A self-sustaining reaction sequence in which a reactive intermediate regenerates itself at each cycle.

initiation → propagation → termination Dimensionless
States of Matter & Gas Laws

Charles's Law

At constant pressure, the volume of a fixed mass of gas is directly proportional to its absolute temperature.

V₁ / T₁ = V₂ / T₂ m³/K
Inorganic & Coordination Chemistry

Chelate Effect

The greater stability of a complex containing a multidentate ligand compared with one containing equivalent monodentate ligands.

ΔS favourable kJ/mol
Foundations of Chemistry

Chemical Formula

A symbolic notation that states which elements a substance contains and in what proportions, using element symbols and subscripts.

Dimensionless
Chemical Kinetics & Catalysis

Chemisorption

Strong adsorption in which actual chemical bonds form between the adsorbate and the surface.

ΔH ≈ −80 to −400 kJ/mol kJ/mol
Chemical Kinetics & Catalysis

Collision Frequency

The number of collisions occurring per unit volume per unit time in a reacting mixture.

Z ∝ n²σ√T s⁻¹
States of Matter & Gas Laws

Compressibility Factor

The ratio of the actual molar volume of a gas to that predicted by the ideal gas law.

Z = pV / nRT Dimensionless
States of Matter & Gas Laws

Condensation

The change of a substance from the gaseous to the liquid state, accompanied by the release of latent heat.

kJ/mol
Chemical Bonding & Molecular Structure

Covalent Bond

A bond formed when two atoms share one or more pairs of electrons so that both achieve a stable configuration.

A· + ·B → A:B kJ/mol