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Results for “Mole”

256 terms · page 10 of 11


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Foundations of Chemistry

Physical Change

A change that alters the form or state of a substance while leaving its chemical composition intact.

Dimensionless
Chemical Bonding & Molecular Structure

Pi Bond

A covalent bond formed by the sideways overlap of parallel p orbitals, with electron density above and below the internuclear axis.

kJ/mol
Acids, Bases & Salts

pKa

The negative logarithm of the acid dissociation constant, giving a convenient scale of acid strength.

pKa = −log Ka Dimensionless
Chemical Bonding & Molecular Structure

Polar Covalent Bond

A covalent bond in which the shared electrons are unequally distributed because the bonded atoms differ in electronegativity.

δ⁺A—Bδ⁻ D
Solutions & Colligative Properties

Positive Deviation

Behaviour in which a solution exerts a higher vapour pressure than Raoult's law predicts.

p > x p° Pa
Stoichiometry & Chemical Reactions

Pyrolysis

The thermal decomposition of a substance at high temperature in the absence of oxygen.

complex → simpler fragments (Δ, no O₂) °C
Organic Chemistry

Racemic Mixture

An equimolar mixture of two enantiomers, which shows no net optical rotation.

50:50 (+) and (−) degrees
Nuclear & Radiochemistry

Radiopharmaceutical

A radioactive compound administered to a patient for diagnosis or treatment.

MBq
Chemical Equilibrium

Relationship between Kp and Kc

The conversion linking the pressure and concentration forms of the equilibrium constant for a gaseous reaction.

Kp = Kc(RT)^Δn Dimensionless
Solutions & Colligative Properties

Relative Lowering of Vapour Pressure

The fractional reduction in a solvent's vapour pressure caused by dissolving a non-volatile solute.

(p° − p) / p° = x_solute Dimensionless
Biochemistry & Polymer Chemistry

RNA

A generally single-stranded nucleic acid that carries out the expression of genetic information.

Dimensionless
Organic Chemistry

Saturation and Unsaturation

The distinction between compounds containing only single bonds and those containing multiple bonds or rings.

DoU = (2C + 2 + N − H − X)/2 Dimensionless
Atomic Structure & Periodicity

Schrödinger Wave Equation

The fundamental equation of quantum mechanics whose solutions give the allowed energies and wavefunctions of a system.

Ĥψ = Eψ J
Chemical Kinetics & Catalysis

Second-Order Reaction

A reaction whose rate depends on the square of one concentration or on the product of two concentrations.

1/[A] = 1/[A]₀ + kt L/(mol·s)
Inorganic & Coordination Chemistry

Secondary Valence

In Werner's theory, the non-ionisable valence corresponding to the coordination number, satisfied by ligands in fixed spatial positions.

Dimensionless
Chemical Kinetics & Catalysis

Selectivity

The ability of a catalyst to direct a reaction towards one particular product among several possible ones.

selectivity = desired product / total product Dimensionless
Foundations of Chemistry

SI Base Units

The seven defined units of the International System from which every other measurement unit is derived.

Various
States of Matter & Gas Laws

Solid State

The state of matter in which particles are held in fixed positions, giving a definite shape and volume.

Dimensionless
Solutions & Colligative Properties

Solubility of Gases

The amount of a gas that dissolves in a given volume of liquid at a stated temperature and partial pressure.

S ∝ p, S decreases with T mol/L
Solutions & Colligative Properties

Solvent

The component of a solution present in the greater amount, which dissolves and disperses the solute.

L
Thermochemistry & Thermodynamics

Specific Heat Capacity

The heat required to raise the temperature of one kilogram of a substance by one kelvin.

c = q / (mΔT) J/(kg·K)
Chemical Bonding & Molecular Structure

sp³ Hybridisation

The mixing of one s and three p orbitals to give four hybrid orbitals directed towards the corners of a tetrahedron.

4 hybrids, 109.5° degrees
Chemical Kinetics & Catalysis

Steric Factor

The fraction of sufficiently energetic collisions that also have the correct spatial orientation for reaction.

p = A / Z Dimensionless
Stoichiometry & Chemical Reactions

Stoichiometric Coefficient

The number written before a formula in a balanced equation, giving the relative amount of that substance consumed or produced.

Dimensionless