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Terms starting with P

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Organic Chemistry

Position Isomerism

Structural isomerism arising from a functional group occupying different positions on the same carbon skeleton.

Dimensionless
Solutions & Colligative Properties

Positive Deviation

Behaviour in which a solution exerts a higher vapour pressure than Raoult's law predicts.

p > x p° Pa
Nuclear & Radiochemistry

Positron Emission

Radioactive decay in which a proton converts into a neutron, emitting a positron and a neutrino.

p → n + e⁺ + ν MeV
Chemical Kinetics & Catalysis

Pre-exponential Factor

The constant A in the Arrhenius equation, representing the frequency of appropriately oriented collisions.

A = pZ Various
Stoichiometry & Chemical Reactions

Precipitate

An insoluble solid that separates from a solution as the result of a chemical reaction.

g
Stoichiometry & Chemical Reactions

Precipitation Reaction

A reaction in which two solutions combine to form an insoluble solid that separates from the mixture.

A⁺(aq) + B⁻(aq) → AB(s) Dimensionless
Analytical Chemistry & Spectroscopy

Precipitation Titration

A titration in which the analyte and titrant combine to form an insoluble product.

Ag⁺ + Cl⁻ → AgCl(s) mol/L
Foundations of Chemistry

Precision

The closeness of repeated measurements of the same quantity to one another, regardless of their accuracy.

RSD = (s / x̄) × 100 Dimensionless
Chemical Equilibrium

Predicting Precipitation

The use of the ionic product and solubility product to decide whether a solid will form on mixing two solutions.

Q_sp > Ksp → precipitate Dimensionless
Chemical Equilibrium

Pressure Equilibrium Constant

The equilibrium constant for a gaseous reaction expressed in terms of partial pressures.

Kp = p_C^c p_D^d / p_A^a p_B^b Various
Electrochemistry & Redox

Primary Cell

A cell in which the electrode reaction is irreversible, so it cannot be recharged.

V
Analytical Chemistry & Spectroscopy

Primary Standard

A highly pure, stable substance that can be weighed accurately and used directly to prepare a solution of known concentration.

g/mol
Biochemistry & Polymer Chemistry

Primary Structure

The linear sequence of amino acids in a polypeptide chain.

Dimensionless
Inorganic & Coordination Chemistry

Primary Valence

In Werner's theory, the ionisable valence of a metal, equal to its oxidation state and satisfied by negative ions.

Dimensionless
Atomic Structure & Periodicity

Principal Quantum Number

The quantum number n that specifies the main energy level and average distance of an electron from the nucleus.

E_n = −13.6 Z² / n² eV Dimensionless
Stoichiometry & Chemical Reactions

Product

A substance formed as a result of a chemical reaction.

mol
Chemical Kinetics & Catalysis

Promoter

A substance that has little catalytic activity itself but greatly increases the effectiveness of a catalyst.

Dimensionless
Biochemistry & Polymer Chemistry

Protein

A large biomolecule made of one or more chains of amino acids folded into a specific three-dimensional shape.

g/mol
Atomic Structure & Periodicity

Proton

A positively charged subatomic particle found in the atomic nucleus, carrying a charge of +1 elementary unit.

m_p = 1.6726 × 10⁻²⁷ kg u
Acids, Bases & Salts

Proton Affinity

The energy released when a gaseous species accepts a proton, measuring intrinsic basicity free of solvent effects.

B(g) + H⁺(g) → BH⁺(g) kJ/mol
Chemical Kinetics & Catalysis

Pseudo-First-Order Reaction

A higher-order reaction that behaves as first order because one reactant is present in such large excess that its concentration is…

rate = k′[A], k′ = k[B]₀ s⁻¹
Foundations of Chemistry

Pure Substance

Matter with a fixed chemical composition and a definite set of physical properties, comprising either a single element or a single compound.

Dimensionless
Foundations of Chemistry

Purity

The mass fraction of the desired substance in a sample, usually expressed as a percentage of the total mass.

purity % = (mass of pure substance / total mass) × 100 Dimensionless
Stoichiometry & Chemical Reactions

Pyrolysis

The thermal decomposition of a substance at high temperature in the absence of oxygen.

complex → simpler fragments (Δ, no O₂) °C