Terms starting with I
53 terms · page 1 of 3
ICE Table
Chemical Equilibrium
mol/L
A systematic tabulation of Initial, Change and Equilibrium amounts used to solve equilibrium problems.
Ideal Gas
States of Matter & Gas Laws
Dimensionless
A hypothetical gas whose particles have zero volume and exert no intermolecular forces, obeying pV = nRT exactly at all conditions.
pV = nRT
Ideal Gas Law
States of Matter & Gas Laws
Various
The equation of state relating the pressure, volume, amount and absolute temperature of an ideal gas.
pV = nRT
Ideal Solution
Solutions & Colligative Properties
Dimensionless
A solution in which the interactions between unlike molecules are identical to those between like molecules, so Raoult's law holds at all compositions.
ΔH_mix = 0, ΔV_mix = 0
Immiscible Liquids
Solutions & Colligative Properties
Dimensionless
Two liquids that do not dissolve in one another and separate into distinct layers.
Incomplete Octet
Chemical Bonding & Molecular Structure
Dimensionless
A stable bonding arrangement in which the central atom carries fewer than eight valence electrons.
Indicator Range
Acids, Bases & Salts
Dimensionless
The span of pH over which an indicator's colour visibly changes, roughly one unit either side of its pKa.
pH = pK_In ± 1
Induced Fit Model
Biochemistry & Polymer Chemistry
Dimensionless
The model in which the active site changes shape on substrate binding to achieve a closer fit.
Inductive Effect
Organic Chemistry
Dimensionless
The permanent polarisation of a sigma bond caused by the differing electronegativity of the attached atoms.
−I and +I effects
Inductively Coupled Plasma Mass Spectrometry
Analytical Chemistry & Spectroscopy
ppb
A technique combining a plasma ion source with a mass spectrometer for ultra-trace multi-element analysis.
Infrared Spectroscopy
Analytical Chemistry & Spectroscopy
cm⁻¹
A technique that identifies functional groups from the infrared frequencies a molecule absorbs as its bonds vibrate.
ν̃ = (1/2πc)√(k/μ)
Inhibitor
Chemical Kinetics & Catalysis
Dimensionless
A substance that decreases the rate of a chemical reaction.
Initial Rate Method
Chemical Kinetics & Catalysis
mol/(L·s)
A technique for determining reaction orders by measuring the starting rate in a series of experiments with different initial concentrations.
rate₂/rate₁ = ([A]₂/[A]₁)^m
Inner Transition Element
Atomic Structure & Periodicity
Dimensionless
An element of the lanthanide or actinide series, in which f orbitals are being filled.
(n−2)f orbitals filling
Instantaneous Rate
Chemical Kinetics & Catalysis
mol/(L·s)
The rate of a reaction at one particular moment, given by the gradient of the concentration–time curve at that point.
rate = d[A]/dt
Integrated Rate Law
Chemical Kinetics & Catalysis
mol/L
The equation obtained by integrating a differential rate law, giving concentration directly as a function of time.
varies with order
Integration in NMR
Analytical Chemistry & Spectroscopy
Dimensionless
The measurement of the area under each NMR signal, which is proportional to the number of nuclei giving rise to it.
area ∝ number of nuclei
Intensive Property
Foundations of Chemistry
Various
A property whose value is independent of the amount of substance present.
Intermolecular Forces
Chemical Bonding & Molecular Structure
kJ/mol
The comparatively weak attractions acting between separate molecules rather than within them.
Internal Energy
Thermochemistry & Thermodynamics
J
The total kinetic and potential energy of all the particles within a system.
ΔU = q + w
Interstitial Compound
Inorganic & Coordination Chemistry
Dimensionless
A compound formed when small atoms occupy the spaces between metal atoms in a lattice.
Interstitial Void
States of Matter & Gas Laws
Dimensionless
An empty space between the packed spheres of a crystal lattice, capable of hosting a smaller ion or atom.
r_void / r_sphere = 0.225 or 0.414
Iodometry
Analytical Chemistry & Spectroscopy
mol/L
A redox titration in which iodine liberated by the analyte is titrated with standard thiosulfate.
I₂ + 2S₂O₃²⁻ → 2I⁻ + S₄O₆²⁻
Ion
Foundations of Chemistry
C (charge)
An atom or group of atoms carrying a net electrical charge because its electron count differs from its proton count.