Terms starting with D
45 terms · page 2 of 2
Diastereomer
Organic Chemistry
Dimensionless
A stereoisomer that is not a mirror image of the compound with which it is compared.
Diffusion
States of Matter & Gas Laws
m²/s
The spontaneous spreading of one substance through another as a result of random molecular motion.
J = −D (dc/dx)
Dilution
Solutions & Colligative Properties
mol/L
The process of reducing a solution's concentration by adding more solvent, leaving the amount of solute unchanged.
M₁V₁ = M₂V₂
Dimensional Analysis
Foundations of Chemistry
Various
A calculation method that tracks and cancels units through a chain of conversion factors to reach the required quantity.
given quantity × (desired unit / given unit) = answer
Dipole Moment
Chemical Bonding & Molecular Structure
D
The vector measure of the separation of positive and negative charge in a bond or molecule.
μ = q × d
Dipole–Dipole Interaction
Chemical Bonding & Molecular Structure
kJ/mol
The electrostatic attraction between the positive end of one polar molecule and the negative end of another.
E ∝ μ₁μ₂ / r³
Diprotic Acid
Acids, Bases & Salts
mol/L
An acid that can donate two protons per molecule.
H₂A ⇌ 2H⁺ + A²⁻
Disaccharide
Biochemistry & Polymer Chemistry
Dimensionless
A carbohydrate formed when two monosaccharide units join through a glycosidic bond.
C₁₂H₂₂O₁₁
Disproportionation Reaction
Stoichiometry & Chemical Reactions
Dimensionless
A redox reaction in which a single species is simultaneously oxidised and reduced.
2A → A⁺ + A⁻
Dissociation
Solutions & Colligative Properties
Dimensionless
The breaking apart of a solute into two or more particles when it dissolves, increasing the effective particle count.
AB → A⁺ + B⁻
Dissociation Constant
Chemical Equilibrium
mol/L
The equilibrium constant for the breaking apart of a compound or complex into smaller species.
Kd = [A][B] / [AB]
Dissolution
Solutions & Colligative Properties
kJ/mol
The process by which a solute disperses into a solvent to form a solution.
Distillation
Foundations of Chemistry
Dimensionless
A separation technique that exploits differences in volatility by vaporising a liquid and condensing the vapour in a separate vessel.
Distribution Law
Chemical Equilibrium
Dimensionless
The principle that a solute distributes itself between two immiscible solvents in a constant ratio at fixed temperature.
K_D = C_organic / C_aqueous
DNA
Biochemistry & Polymer Chemistry
Dimensionless
The double-stranded nucleic acid that carries the hereditary information of almost all living organisms.
Double Displacement Reaction
Stoichiometry & Chemical Reactions
Dimensionless
A reaction in which two compounds exchange partner ions to form two new compounds.
AB + CD → AD + CB
Double Helix
Biochemistry & Polymer Chemistry
nm
The structure of DNA, in which two antiparallel polynucleotide strands wind around a common axis.
10.5 base pairs per turn
Double Salt
Acids, Bases & Salts
Dimensionless
A salt containing two different cations or anions that dissociates completely into all its constituent ions in solution.
e.g. K₂SO₄·Al₂(SO₄)₃·24H₂O
Dry Cell
Electrochemistry & Redox
V
A primary cell using a moist paste rather than a liquid electrolyte, so it can be used in any orientation.
Zn + 2MnO₂ + 2NH₄⁺ → Zn²⁺ + Mn₂O₃ + 2NH₃ + H₂O
Dynamic Equilibrium
Chemical Equilibrium
Dimensionless
An equilibrium in which opposing processes continue at the molecular level but at equal and opposite rates.
rate_forward = rate_reverse
d–d Transition
Inorganic & Coordination Chemistry
nm
The promotion of an electron between split d orbitals, responsible for the characteristic colours of transition metal complexes.
ΔE = hν = Δ