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Chemical Bonding & Molecular Structure

Dipole Moment

The vector measure of the separation of positive and negative charge in a bond or molecule.

Formula / equation μ = q × d
Unit D

In depth

Measured in debye, the dipole moment is the vector sum of all bond dipoles and lone-pair contributions, so a molecule with polar bonds can still be non-polar if the geometry is symmetric. Dipole moments determine solubility patterns, boiling points and how a substance responds to an electric field.

Examples in the real world

Water 1.85 D and NH₃ 1.47 D are polar; CO₂ and CCl₄ measure 0 D because their bond dipoles cancel.