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Acids, Bases & Salts

Double Salt

A salt containing two different cations or anions that dissociates completely into all its constituent ions in solution.

Formula / equation e.g. K₂SO₄·Al₂(SO₄)₃·24H₂O
Unit Dimensionless

In depth

Double salts exist only in the solid state, where the two component salts crystallise together in a fixed ratio. On dissolution they simply release all their ions, so their solutions show the ordinary reactions of each ion present.

Examples in the real world

Potash alum giving K⁺, Al³⁺ and SO₄²⁻ ions; Mohr's salt giving Fe²⁺, NH₄⁺ and sulfate.