Results for “Mole”
18 terms
Acid Strength and Molecular Structure
Acids, Bases & Salts
Dimensionless
The structural factors that determine how readily a molecule releases a proton.
Antibonding Molecular Orbital
Chemical Bonding & Molecular Structure
Dimensionless
A molecular orbital higher in energy than its parent atomic orbitals, whose occupation destabilises the molecule.
ψ* = ψ_A − ψ_B
Active Site
Chemical Kinetics & Catalysis
Dimensionless
The specific region of a catalyst or enzyme at which the reacting molecules bind and are transformed.
Addition Reaction
Stoichiometry & Chemical Reactions
Dimensionless
A reaction in which two molecules combine to form a single larger product, with no atoms left over.
A + B → AB
Adsorption
Chemical Kinetics & Catalysis
mol/g
The accumulation of molecules of a gas or liquid on the surface of a solid.
Anion
Foundations of Chemistry
C (charge)
A negatively charged ion produced when an atom or molecule gains one or more electrons.
X + n e⁻ → Xⁿ⁻
Aromaticity
Organic Chemistry
kJ/mol
The special stability of planar cyclic molecules with a continuous, fully conjugated system of delocalised pi electrons.
planar, cyclic, conjugated, 4n+2 π
Association
Solutions & Colligative Properties
Dimensionless
The joining of solute molecules in solution into larger aggregates, reducing the effective number of particles.
nA → Aₙ
Atomicity
Foundations of Chemistry
Dimensionless
The number of atoms present in one molecule of an element.
Avogadro's Law
States of Matter & Gas Laws
L/mol
Equal volumes of all gases at the same temperature and pressure contain equal numbers of molecules.
V ∝ n
Avogadro's Number
Foundations of Chemistry
mol⁻¹
The number of elementary entities in one mole of substance, fixed by definition at 6.02214076 × 10²³ mol⁻¹.
N = n × N_A
Abnormal Molar Mass
Solutions & Colligative Properties
g/mol
A molar mass value obtained from colligative measurements that differs from the true value because the solute associates or dissociates.
M_normal = i × M_observed
Aldol Condensation
Organic Chemistry
Dimensionless
The base-catalysed reaction of two carbonyl compounds to give a beta-hydroxy carbonyl, which often dehydrates to an enone.
2RCH₂CHO → RCH₂CH(OH)CHRCHO
Amphoteric Substance
Acids, Bases & Salts
Dimensionless
A substance able to react as either an acid or a base depending on what it meets.
Association Constant
Chemical Equilibrium
L/mol
The equilibrium constant for the combination of two species into a single associated entity, the reciprocal of the dissociation constant.
Ka = 1 / Kd
Atomic Mass Unit
Foundations of Chemistry
u (Da)
A mass unit defined as exactly one twelfth the mass of a free, unbound carbon-12 atom in its ground state.
1 u = 1.66053907 × 10⁻²⁷ kg
Atomic Orbital
Atomic Structure & Periodicity
Dimensionless
A mathematical function describing the region around a nucleus where an electron of given energy is most likely to be found.
|ψ|² = probability density
Average Kinetic Energy
States of Matter & Gas Laws
J
The mean translational kinetic energy of the particles in a sample, dependent only on absolute temperature.
KE = (3/2)kT per molecule