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Foundations of Chemistry

Anion

A negatively charged ion produced when an atom or molecule gains one or more electrons.

Formula / equation X + n e⁻ → Xⁿ⁻
Unit C (charge)

In depth

Anions are larger than their parent atoms because the added electrons increase mutual repulsion while the nuclear charge stays fixed. Non-metals with high electron affinities form anions readily. During electrolysis anions travel to the positively charged anode.

Examples in the real world

Cl⁻, O²⁻, S²⁻, and the polyatomic nitrate NO₃⁻ and carbonate CO₃²⁻ ions.