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Thermochemistry & Thermodynamics

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Thermochemistry & Thermodynamics

Second Law of Thermodynamics

The total entropy of the universe increases in every spontaneous process.

ΔS_universe > 0 J/K
Thermochemistry & Thermodynamics

Specific Heat Capacity

The heat required to raise the temperature of one kilogram of a substance by one kelvin.

c = q / (mΔT) J/(kg·K)
Thermochemistry & Thermodynamics

Spontaneity

The tendency of a process to occur without any continuous external input of energy.

ΔG < 0 kJ/mol
Thermochemistry & Thermodynamics

Standard Enthalpy of Combustion

The enthalpy change when one mole of a substance burns completely in excess oxygen under standard conditions.

ΔH_c° kJ/mol
Thermochemistry & Thermodynamics

Standard Enthalpy of Formation

The enthalpy change when one mole of a compound forms from its elements in their standard states.

ΔH_f° kJ/mol
Thermochemistry & Thermodynamics

Standard Molar Entropy

The absolute entropy of one mole of a substance in its standard state at 298 K.

ΔS° = ΣS°(products) − ΣS°(reactants) J/(mol·K)
Thermochemistry & Thermodynamics

Standard State

The reference condition of a pure substance at 1 bar pressure and a stated temperature, conventionally 298.15 K.

denoted by ° Dimensionless
Thermochemistry & Thermodynamics

State Function

A property whose value depends only on the current state of the system, not on how that state was reached.

ΔX = X_final − X_initial Various
Thermochemistry & Thermodynamics

Surroundings

Everything outside the chosen system with which it can exchange energy or matter.

Dimensionless
Thermochemistry & Thermodynamics

System

The specific part of the universe chosen for thermodynamic study, separated from everything else by a real or imaginary boundary.

Dimensionless