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Thermochemistry & Thermodynamics

Thermodynamics

The branch of science dealing with energy, its transformations, and the direction in which processes occur.

Unit J

In depth

Chemical thermodynamics predicts whether a reaction is possible and how far it will go, using only bulk properties measured at the start and end. It says nothing about how fast a change occurs — that is the province of kinetics — so a reaction can be thermodynamically favourable yet immeasurably slow.

Examples in the real world

Predicting that diamond is thermodynamically unstable relative to graphite, though the conversion takes geological time.