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Electrochemistry & Redox

Standard Electrode Potential

The potential of a half-cell measured against the standard hydrogen electrode under standard conditions.

Formula / equation E° at 298 K, 1 M, 1 bar
Unit V

In depth

By convention these are quoted as reduction potentials, so a more positive value indicates a stronger tendency to be reduced and hence a stronger oxidising agent. Because only differences are measurable, all values are relative to the arbitrary zero of the hydrogen electrode.

Examples in the real world

F₂/F⁻ at +2.87 V is the strongest common oxidant; Li⁺/Li at −3.04 V is the strongest reductant.