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Stoichiometry & Chemical Reactions

Excess Reagent

A reactant present in a greater amount than is needed to consume the limiting reagent completely.

Formula / equation n_excess = n_initial − n_reacted
Unit mol

In depth

Some of an excess reagent remains unreacted at the end and must be separated from the product. Chemists deliberately use an excess of a cheap or easily removed reactant to drive an expensive one to complete conversion, a strategy justified by Le Chatelier's principle in reversible systems.

Examples in the real world

Burning a hydrocarbon in excess air ensures complete combustion; leftover oxygen is simply vented.