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Stoichiometry & Chemical Reactions

Gay-Lussac's Law of Combining Volumes

The principle that gases react in volume ratios that are simple whole numbers, when measured at the same temperature and pressure.

Formula / equation V_A : V_B = a : b
Unit L

In depth

Combined with Avogadro's hypothesis that equal volumes contain equal numbers of molecules, the law proved that elemental gases such as hydrogen and oxygen must be diatomic. For gaseous reactions it allows stoichiometry to be done directly in volumes, with no need to convert to moles.

Examples in the real world

Two volumes of hydrogen combine with one of oxygen to give two volumes of steam, a clean 2:1:2 ratio.