Results for “Mole”
256 terms · page 7 of 11
Abnormal Molar Mass
Solutions & Colligative Properties
g/mol
A molar mass value obtained from colligative measurements that differs from the true value because the solute associates or dissociates.
M_normal = i × M_observed
Aldol Condensation
Organic Chemistry
Dimensionless
The base-catalysed reaction of two carbonyl compounds to give a beta-hydroxy carbonyl, which often dehydrates to an enone.
2RCH₂CHO → RCH₂CH(OH)CHRCHO
Amphoteric Substance
Acids, Bases & Salts
Dimensionless
A substance able to react as either an acid or a base depending on what it meets.
Association Constant
Chemical Equilibrium
L/mol
The equilibrium constant for the combination of two species into a single associated entity, the reciprocal of the dissociation constant.
Ka = 1 / Kd
Atomic Mass Unit
Foundations of Chemistry
u (Da)
A mass unit defined as exactly one twelfth the mass of a free, unbound carbon-12 atom in its ground state.
1 u = 1.66053907 × 10⁻²⁷ kg
Atomic Orbital
Atomic Structure & Periodicity
Dimensionless
A mathematical function describing the region around a nucleus where an electron of given energy is most likely to be found.
|ψ|² = probability density
Average Kinetic Energy
States of Matter & Gas Laws
J
The mean translational kinetic energy of the particles in a sample, dependent only on absolute temperature.
KE = (3/2)kT per molecule
Base Peak
Analytical Chemistry & Spectroscopy
Dimensionless
The most intense peak in a mass spectrum, assigned an arbitrary relative abundance of 100%.
Biochemistry
Biochemistry & Polymer Chemistry
Dimensionless
The study of the chemical substances and processes that occur within living organisms.
Boiling Point
States of Matter & Gas Laws
°C
The temperature at which the vapour pressure of a liquid equals the external pressure acting on it.
p_vap = p_external
Bonding Pair
Chemical Bonding & Molecular Structure
Dimensionless
A pair of electrons shared between two atoms and responsible for holding them together.
Boyle's Law
States of Matter & Gas Laws
Pa·m³
At constant temperature, the volume of a fixed mass of gas is inversely proportional to its pressure.
p₁V₁ = p₂V₂
Calorific Value
Thermochemistry & Thermodynamics
kJ/g
The heat released by the complete combustion of unit mass of a fuel.
CV = ΔH_c / molar mass
Cannizzaro Reaction
Organic Chemistry
Dimensionless
The disproportionation of an aldehyde with no alpha hydrogen under concentrated alkali into an alcohol and a carboxylate.
2RCHO + OH⁻ → RCH₂OH + RCOO⁻
Chain Isomerism
Organic Chemistry
Dimensionless
Structural isomerism arising from different arrangements of the carbon skeleton.
Chain Reaction
Chemical Kinetics & Catalysis
Dimensionless
A self-sustaining reaction sequence in which a reactive intermediate regenerates itself at each cycle.
initiation → propagation → termination
Charles's Law
States of Matter & Gas Laws
m³/K
At constant pressure, the volume of a fixed mass of gas is directly proportional to its absolute temperature.
V₁ / T₁ = V₂ / T₂
Chelate Effect
Inorganic & Coordination Chemistry
kJ/mol
The greater stability of a complex containing a multidentate ligand compared with one containing equivalent monodentate ligands.
ΔS favourable
Chemical Formula
Foundations of Chemistry
Dimensionless
A symbolic notation that states which elements a substance contains and in what proportions, using element symbols and subscripts.
Chemisorption
Chemical Kinetics & Catalysis
kJ/mol
Strong adsorption in which actual chemical bonds form between the adsorbate and the surface.
ΔH ≈ −80 to −400 kJ/mol
Collision Frequency
Chemical Kinetics & Catalysis
s⁻¹
The number of collisions occurring per unit volume per unit time in a reacting mixture.
Z ∝ n²σ√T
Compressibility Factor
States of Matter & Gas Laws
Dimensionless
The ratio of the actual molar volume of a gas to that predicted by the ideal gas law.
Z = pV / nRT
Condensation
States of Matter & Gas Laws
kJ/mol
The change of a substance from the gaseous to the liquid state, accompanied by the release of latent heat.
Covalent Bond
Chemical Bonding & Molecular Structure
kJ/mol
A bond formed when two atoms share one or more pairs of electrons so that both achieve a stable configuration.
A· + ·B → A:B