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291 terms · page 5 of 13


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Analytical Chemistry & Spectroscopy

Atomic Absorption Spectroscopy

A technique that measures the concentration of a metal from the light its free gaseous atoms absorb.

A = εlc ppm
Atomic Structure & Periodicity

Atomic Orbital

A mathematical function describing the region around a nucleus where an electron of given energy is most likely to be found.

|ψ|² = probability density Dimensionless
Foundations of Chemistry

Atomicity

The number of atoms present in one molecule of an element.

Dimensionless
Acids, Bases & Salts

Basic Solution

A solution in which the hydroxide ion concentration exceeds the hydrogen ion concentration.

[OH⁻] > [H⁺] mol/L
States of Matter & Gas Laws

Boiling Point

The temperature at which the vapour pressure of a liquid equals the external pressure acting on it.

p_vap = p_external °C
Solutions & Colligative Properties

Boiling Point Elevation

The rise in a solvent's boiling point caused by the presence of a non-volatile solute.

ΔT_b = i K_b m °C
Chemical Bonding & Molecular Structure

Bond Polarity

The degree of unequal electron sharing in a covalent bond, arising from an electronegativity difference between the bonded atoms.

Δχ = |χ_A − χ_B| Dimensionless
Organic Chemistry

Carbanion

An organic ion in which a carbon atom bears a negative charge and a lone pair.

R₃C⁻ Dimensionless
Chemical Kinetics & Catalysis

Catalysis

The process by which a reaction rate is increased through the action of a catalyst.

Dimensionless
Biochemistry & Polymer Chemistry

Cellular Respiration

The oxidation of nutrients within cells to release energy as ATP.

C₆H₁₂O₆ + 6O₂ → 6CO₂ + 6H₂O kJ/mol
Chemical Kinetics & Catalysis

Chain Reaction

A self-sustaining reaction sequence in which a reactive intermediate regenerates itself at each cycle.

initiation → propagation → termination Dimensionless
Stoichiometry & Chemical Reactions

Chemical Equation

A symbolic representation of a chemical reaction showing reactants on the left and products on the right.

aA + bB → cC + dD Dimensionless
Foundations of Chemistry

Chemical Property

A characteristic that describes how a substance transforms into a different substance, observable only during a chemical reaction.

Various
Chemical Kinetics & Catalysis

Chemisorption

Strong adsorption in which actual chemical bonds form between the adsorbate and the surface.

ΔH ≈ −80 to −400 kJ/mol kJ/mol
Analytical Chemistry & Spectroscopy

Complexometric Titration

A titration based on the formation of a stable complex between the analyte metal ion and a chelating titrant.

M²⁺ + EDTA⁴⁻ → [M(EDTA)]²⁻ mol/L
Foundations of Chemistry

Compound

A pure substance formed when two or more different elements combine chemically in a fixed, whole-number mass ratio.

Dimensionless
Inorganic & Coordination Chemistry

Coordination Isomerism

Isomerism in compounds containing both a complex cation and a complex anion, where ligands are distributed differently between them.

Dimensionless
Nuclear & Radiochemistry

Critical Mass

The minimum mass of fissile material needed to sustain a nuclear chain reaction.

kg
Solutions & Colligative Properties

Cryoscopic Constant

The freezing point depression produced by a one-molal solution of a non-electrolyte in a given solvent.

K_f = RT_f²M / ΔH_fus K·kg/mol
Chemical Bonding & Molecular Structure

Crystal Lattice

The regular, repeating three-dimensional arrangement of particles in a crystalline solid.

Dimensionless
States of Matter & Gas Laws

Crystalline Solid

A solid in which the constituent particles are arranged in a regular, repeating three-dimensional pattern extending over long distances.

Dimensionless
Electrochemistry & Redox

Daniell Cell

The classic galvanic cell consisting of a zinc electrode in zinc sulfate and a copper electrode in copper sulfate.

Zn + Cu²⁺ → Zn²⁺ + Cu, E° = 1.10 V V
Chemical Equilibrium

Debye–Hückel Limiting Law

The theoretical relation predicting activity coefficients of ions in very dilute solution from their charge and the ionic strength.

log γ = −A z² √I Dimensionless
Foundations of Chemistry

Decantation

The separation of a liquid from a settled solid or a denser immiscible liquid by carefully pouring off the upper layer.

Dimensionless