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States of Matter & Gas Laws

Van der Waals Equation

A modified equation of state that corrects the ideal gas law for molecular volume and intermolecular attraction.

(p + an²/V²)(V − nb) = nRT Various
Chemical Bonding & Molecular Structure

Van der Waals Forces

The collective name for the weak attractive forces between molecules arising from dipole interactions.

E ∝ 1 / r⁶ kJ/mol
Chemical Equilibrium

Van't Hoff Equation

The equation describing how an equilibrium constant varies with temperature.

ln(K₂/K₁) = −ΔH°/R (1/T₂ − 1/T₁) kJ/mol
Solutions & Colligative Properties

Van't Hoff Factor

The ratio of the actual number of particles produced in solution to the number of formula units dissolved.

i = observed ΔT / calculated ΔT Dimensionless
States of Matter & Gas Laws

Vapour Pressure

The pressure exerted by a vapour in dynamic equilibrium with its liquid or solid at a given temperature.

ln p = −ΔH_vap / RT + C Pa
Chemical Equilibrium

Vapour–Liquid Equilibrium

The equilibrium between a liquid and its vapour in a closed container at a given temperature.

p = p_saturated Pa
States of Matter & Gas Laws

Viscosity

A liquid's resistance to flow, arising from internal friction between adjacent layers of molecules.

F = ηA (dv/dx) Pa·s
Biochemistry & Polymer Chemistry

Vitamin

An organic compound required in small amounts that an organism cannot synthesise for itself.

mg
Solutions & Colligative Properties

Volume Percentage

The volume of a liquid solute expressed as a percentage of the total volume of solution.

% v/v = (V_solute / V_solution) × 100 Dimensionless
Analytical Chemistry & Spectroscopy

Volumetric Analysis

Quantitative analysis based on measuring the volume of a standard solution needed to react with the analyte.

n = M × V mL
Chemical Bonding & Molecular Structure

VSEPR Theory

The model that predicts molecular shape by arranging valence electron pairs around a central atom so their mutual repulsion is minimised.

AXₘEₙ notation Dimensionless
Biochemistry & Polymer Chemistry

Vulcanisation

The treatment of natural rubber with sulfur to form cross-links that greatly improve its properties.

Dimensionless
Foundations of Chemistry

Water of Crystallisation

Water molecules chemically bound within the crystal lattice of a hydrated salt in a fixed stoichiometric ratio.

mol per mol
Acids, Bases & Salts

Weak Acid

An acid that ionises only partially in aqueous solution, establishing an equilibrium with its conjugate base.

HA ⇌ H⁺ + A⁻ mol/L
Acids, Bases & Salts

Weak Base

A base that accepts protons only partially in aqueous solution, establishing an equilibrium.

B + H₂O ⇌ BH⁺ + OH⁻ mol/L
Inorganic & Coordination Chemistry

Weak Field Ligand

A ligand that produces only a small crystal field splitting, so electrons occupy upper orbitals rather than pairing.

Δ < P cm⁻¹
Inorganic & Coordination Chemistry

Werner's Theory

The 1893 theory proposing that metals exhibit two types of valence and that ligands occupy fixed positions in space around the metal.

Dimensionless
Thermochemistry & Thermodynamics

Work

Energy transferred when a force moves through a distance, most often in chemistry as a gas expanding against external pressure.

w = −p_ext ΔV J
Analytical Chemistry & Spectroscopy

X-ray Crystallography

A technique that determines the three-dimensional atomic structure of a crystal from its X-ray diffraction pattern.

nλ = 2d sin θ pm
Organic Chemistry

Zaitsev's Rule

In an elimination reaction, the major product is usually the more highly substituted and therefore more stable alkene.

Dimensionless
Chemical Kinetics & Catalysis

Zero-Order Reaction

A reaction whose rate is independent of the concentration of the reactant.

[A] = [A]₀ − kt mol/(L·s)
Thermochemistry & Thermodynamics

Zeroth Law of Thermodynamics

If two systems are each in thermal equilibrium with a third, they are in thermal equilibrium with each other.

T_A = T_C and T_B = T_C ⟹ T_A = T_B K
Inorganic & Coordination Chemistry

Zone Refining

An ultra-purification technique in which a narrow molten zone is passed repeatedly along a solid rod.

Dimensionless
Biochemistry & Polymer Chemistry

Zwitterion

A molecule carrying both a positive and a negative charge but no net overall charge.

⁺H₃N–CHR–COO⁻ Dimensionless