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A–Z
All A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
Solutions & Colligative Properties

Negative Deviation

Behaviour in which a solution exerts a lower vapour pressure than Raoult's law predicts.

p < x p° Pa
Electrochemistry & Redox

Nernst Equation

The equation relating a cell's potential to the concentrations of the species involved.

E = E° − (RT/nF) ln Q V
Stoichiometry & Chemical Reactions

Net Ionic Equation

An equation showing only the species that actually change during a reaction, with all spectator ions removed.

Ag⁺(aq) + Cl⁻(aq) → AgCl(s) Dimensionless
Acids, Bases & Salts

Neutral Salt

A salt whose aqueous solution has a pH of 7 because neither of its ions hydrolyses appreciably.

Dimensionless
Acids, Bases & Salts

Neutral Solution

A solution in which the concentrations of hydrogen and hydroxide ions are exactly equal.

[H⁺] = [OH⁻] = √Kw mol/L
Stoichiometry & Chemical Reactions

Neutralisation Reaction

The reaction between an acid and a base to produce a salt and water.

HA + BOH → BA + H₂O kJ/mol
Atomic Structure & Periodicity

Neutron

An electrically neutral subatomic particle found in the nucleus, with a mass slightly greater than that of a proton.

m_n = 1.6749 × 10⁻²⁷ kg u
Nuclear & Radiochemistry

Neutron Emission

The direct ejection of a neutron from an extremely neutron-rich nucleus.

ᴬ_Z X → ᴬ⁻¹_Z X + ¹₀n MeV
Nuclear & Radiochemistry

Neutron-to-Proton Ratio

The ratio of neutrons to protons in a nucleus, the principal determinant of its stability and decay mode.

N / Z Dimensionless
Organic Chemistry

Nitrile

A compound containing a carbon–nitrogen triple bond.

R–C≡N Dimensionless
Atomic Structure & Periodicity

Noble Gases

The group 18 elements, whose completely filled valence shells make them exceptionally unreactive.

ns² np⁶ (He is 1s²) Dimensionless
Atomic Structure & Periodicity

Node

A region within an orbital where the probability of finding an electron falls to zero.

total nodes = n − 1 Dimensionless
Solutions & Colligative Properties

Non-Ideal Solution

A solution that departs from Raoult's law because interactions between unlike molecules differ from those between like molecules.

p ≠ x p° Pa
Solutions & Colligative Properties

Normality

The concentration of a solution expressed as gram equivalents of solute per litre of solution.

N = M × n-factor N (equiv/L)
Nuclear & Radiochemistry

Nuclear Binding Energy

The energy that would be required to separate a nucleus completely into its individual protons and neutrons.

E = Δm c² MeV
Nuclear & Radiochemistry

Nuclear Chain Reaction

A self-sustaining sequence of fissions in which neutrons released by one event trigger further events.

k = neutrons produced / neutrons lost Dimensionless
Nuclear & Radiochemistry

Nuclear Chemistry

The study of changes that occur in atomic nuclei and of the properties of radioactive substances.

Dimensionless
Nuclear & Radiochemistry

Nuclear Cross Section

A measure of the probability that a particular nuclear reaction will occur between a nucleus and an incident particle.

σ, measured in barns barn
Nuclear & Radiochemistry

Nuclear Fission

The splitting of a heavy nucleus into two lighter nuclei with the release of neutrons and a large amount of energy.

²³⁵U + n → fragments + 2–3n + energy MeV
Nuclear & Radiochemistry

Nuclear Fuel Enrichment

The process of increasing the proportion of a fissile isotope above its natural abundance.

Dimensionless
Nuclear & Radiochemistry

Nuclear Fusion

The combining of light nuclei into a heavier one, releasing energy.

²H + ³H → ⁴He + n + 17.6 MeV MeV
Nuclear & Radiochemistry

Nuclear Isomer

A nucleus in a long-lived excited state that decays to its ground state by gamma emission.

denoted with m, e.g. ⁹⁹ᵐTc MeV
Analytical Chemistry & Spectroscopy

Nuclear Magnetic Resonance Spectroscopy

A technique that probes molecular structure using the resonance of atomic nuclei in a strong magnetic field.

ν = γB₀ / 2π MHz
Nuclear & Radiochemistry

Nuclear Reactor

A device in which a controlled nuclear chain reaction generates heat for power or produces radioisotopes.

MW