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Analytical Chemistry & Spectroscopy

High-Performance Liquid Chromatography

A technique in which a liquid mobile phase is pumped at high pressure through a column of very fine stationary phase.

min
Analytical Chemistry & Spectroscopy

High-Resolution Mass Spectrometry

Mass spectrometry capable of measuring mass to four or more decimal places, allowing molecular formulae to be determined.

Da
Chemical Bonding & Molecular Structure

HOMO and LUMO

The highest occupied and lowest unoccupied molecular orbitals, which together govern a molecule's reactivity and spectroscopy.

ΔE = E_LUMO − E_HOMO eV
Chemical Kinetics & Catalysis

Homogeneous Catalysis

Catalysis in which the catalyst is in the same phase as the reactants.

Dimensionless
Chemical Equilibrium

Homogeneous Equilibrium

An equilibrium in which all the reacting species are present in the same phase.

Dimensionless
Foundations of Chemistry

Homogeneous Mixture

A mixture whose composition and properties are uniform throughout, with no visible boundary between the components.

Dimensionless
Organic Chemistry

Homologous Series

A family of compounds sharing the same functional group and general formula, with successive members differing by CH₂.

differ by −CH₂− Dimensionless
Biochemistry & Polymer Chemistry

Hormone

A chemical messenger released by one tissue that regulates the activity of cells elsewhere in the body.

mol/L
Atomic Structure & Periodicity

Hund's Rule of Maximum Multiplicity

The rule that electrons occupy degenerate orbitals singly with parallel spins before any orbital is doubly occupied.

maximise total spin S Dimensionless
Chemical Bonding & Molecular Structure

Hybridisation

The mixing of atomic orbitals on the same atom to form an equal number of new, equivalent orbitals suited to bonding.

Dimensionless
Foundations of Chemistry

Hydrate

A crystalline compound in which a definite number of water molecules is incorporated into the lattice.

MX·nH₂O Dimensionless
Inorganic & Coordination Chemistry

Hydrate Isomerism

Isomerism arising from water molecules occupying either the coordination sphere or lattice positions outside it.

Dimensionless
Solutions & Colligative Properties

Hydration Energy

The energy released when one mole of gaseous ions is surrounded by water molecules to form a dilute aqueous solution.

ΔH_hyd ∝ z / r kJ/mol
Stoichiometry & Chemical Reactions

Hydration Reaction

The addition of water across a multiple bond or the incorporation of water into a crystal lattice.

C=C + H₂O → C(OH)–CH Dimensionless
Organic Chemistry

Hydrocarbon

A compound composed exclusively of carbon and hydrogen.

CₓH_y Dimensionless
Chemical Bonding & Molecular Structure

Hydrogen Bond

A strong dipole interaction between a hydrogen atom bonded to N, O or F and a lone pair on another such atom.

X–H···Y (X, Y = N, O, F) kJ/mol
Electrochemistry & Redox

Hydrogen–Oxygen Fuel Cell

A fuel cell in which hydrogen is oxidised at the anode and oxygen reduced at the cathode, producing only water.

2H₂ + O₂ → 2H₂O, E° = 1.23 V V
Stoichiometry & Chemical Reactions

Hydrolysis

A reaction in which a bond is cleaved by water, with the H and OH fragments adding to the two products.

AB + H₂O → AOH + BH Dimensionless
Acids, Bases & Salts

Hydrolysis Constant

The equilibrium constant for the hydrolysis of a salt ion in water.

Kh = Kw / Ka (anion) mol/L
Organic Chemistry

Hyperconjugation

The stabilising delocalisation of electrons from a sigma C–H bond into an adjacent empty or partly filled p orbital.

kJ/mol
Solutions & Colligative Properties

Hypertonic Solution

A solution with a higher osmotic pressure than the one it is compared with, drawing water out of the more dilute side.

π_solution > π_cell atm
Solutions & Colligative Properties

Hypotonic Solution

A solution with a lower osmotic pressure than the one it is compared with, so water flows into the more concentrated side.

π_solution < π_cell atm
Organic Chemistry

Hückel's Rule

The rule that a planar cyclic conjugated system is aromatic if it contains 4n + 2 pi electrons.

4n + 2 π electrons Dimensionless
Chemical Equilibrium

ICE Table

A systematic tabulation of Initial, Change and Equilibrium amounts used to solve equilibrium problems.

mol/L