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Acids, Bases & Salts

Degree of Hydrolysis

The fraction of a salt's ions that have reacted with water at equilibrium.

h = √(Kh / c) Dimensionless
Acids, Bases & Salts

Degree of Ionisation

The fraction of dissolved electrolyte molecules that have broken into ions at equilibrium.

α = ionised / total Dimensionless
Biochemistry & Polymer Chemistry

Degree of Polymerisation

The number of monomer units in an average polymer chain.

DP = M_polymer / M_monomer Dimensionless
Stoichiometry & Chemical Reactions

Dehydration Reaction

A reaction in which water is removed from a single molecule, generally producing an unsaturated or condensed product.

R–CH₂–CH₂OH → R–CH=CH₂ + H₂O Dimensionless
Foundations of Chemistry

Deliquescence

The property of a solid that absorbs enough water vapour from the air to dissolve completely in the water it takes up.

Dimensionless
Chemical Bonding & Molecular Structure

Delocalisation

The spreading of electrons over three or more atoms rather than their confinement between two.

Dimensionless
Biochemistry & Polymer Chemistry

Denaturation

The loss of a protein's native three-dimensional structure without breaking its peptide bonds.

Dimensionless
Foundations of Chemistry

Density

The mass of a substance contained in a unit volume, a characteristic intensive property of each material.

ρ = m / V g/cm³
Inorganic & Coordination Chemistry

Denticity

The number of donor atoms a single ligand uses to bind to one metal centre.

κⁿ or ηⁿ notation Dimensionless
States of Matter & Gas Laws

Deposition

The direct conversion of a vapour into a solid without an intermediate liquid phase.

kJ/mol
Atomic Structure & Periodicity

Diagonal Relationship

The similarity in properties between an element of period 2 and the element one place to its lower right in period 3.

Dimensionless
Atomic Structure & Periodicity

Diamagnetism

Weak repulsion from a magnetic field, shown by substances in which all electrons are spin-paired.

μ = 0 BM BM
Organic Chemistry

Diastereomer

A stereoisomer that is not a mirror image of the compound with which it is compared.

Dimensionless
States of Matter & Gas Laws

Diffusion

The spontaneous spreading of one substance through another as a result of random molecular motion.

J = −D (dc/dx) m²/s
Solutions & Colligative Properties

Dilution

The process of reducing a solution's concentration by adding more solvent, leaving the amount of solute unchanged.

M₁V₁ = M₂V₂ mol/L
Foundations of Chemistry

Dimensional Analysis

A calculation method that tracks and cancels units through a chain of conversion factors to reach the required quantity.

given quantity × (desired unit / given unit) = answer Various
Chemical Bonding & Molecular Structure

Dipole Moment

The vector measure of the separation of positive and negative charge in a bond or molecule.

μ = q × d D
Chemical Bonding & Molecular Structure

Dipole–Dipole Interaction

The electrostatic attraction between the positive end of one polar molecule and the negative end of another.

E ∝ μ₁μ₂ / r³ kJ/mol
Acids, Bases & Salts

Diprotic Acid

An acid that can donate two protons per molecule.

H₂A ⇌ 2H⁺ + A²⁻ mol/L
Biochemistry & Polymer Chemistry

Disaccharide

A carbohydrate formed when two monosaccharide units join through a glycosidic bond.

C₁₂H₂₂O₁₁ Dimensionless
Stoichiometry & Chemical Reactions

Disproportionation Reaction

A redox reaction in which a single species is simultaneously oxidised and reduced.

2A → A⁺ + A⁻ Dimensionless
Solutions & Colligative Properties

Dissociation

The breaking apart of a solute into two or more particles when it dissolves, increasing the effective particle count.

AB → A⁺ + B⁻ Dimensionless
Chemical Equilibrium

Dissociation Constant

The equilibrium constant for the breaking apart of a compound or complex into smaller species.

Kd = [A][B] / [AB] mol/L
Solutions & Colligative Properties

Dissolution

The process by which a solute disperses into a solvent to form a solution.

kJ/mol