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Atomic Structure & Periodicity

Diamagnetism

Weak repulsion from a magnetic field, shown by substances in which all electrons are spin-paired.

Formula / equation μ = 0 BM
Unit BM

In depth

An applied field induces electron currents that oppose it, producing a small negative susceptibility. Diamagnetism is present in all matter but is masked whenever unpaired electrons make a sample paramagnetic. Its detection therefore proves that every electron in the species is paired.

Examples in the real world

N₂, water and benzene are all diamagnetic; the low-spin complex [Fe(CN)₆]⁴⁻ is diamagnetic while [Fe(H₂O)₆]²⁺ is not.