Results for “Mole”
256 terms · page 10 of 11
Physical Change
Foundations of Chemistry
Dimensionless
A change that alters the form or state of a substance while leaving its chemical composition intact.
Pi Bond
Chemical Bonding & Molecular Structure
kJ/mol
A covalent bond formed by the sideways overlap of parallel p orbitals, with electron density above and below the internuclear axis.
pKa
Acids, Bases & Salts
Dimensionless
The negative logarithm of the acid dissociation constant, giving a convenient scale of acid strength.
pKa = −log Ka
Polar Covalent Bond
Chemical Bonding & Molecular Structure
D
A covalent bond in which the shared electrons are unequally distributed because the bonded atoms differ in electronegativity.
δ⁺A—Bδ⁻
Positive Deviation
Solutions & Colligative Properties
Pa
Behaviour in which a solution exerts a higher vapour pressure than Raoult's law predicts.
p > x p°
Pyrolysis
Stoichiometry & Chemical Reactions
°C
The thermal decomposition of a substance at high temperature in the absence of oxygen.
complex → simpler fragments (Δ, no O₂)
Racemic Mixture
Organic Chemistry
degrees
An equimolar mixture of two enantiomers, which shows no net optical rotation.
50:50 (+) and (−)
Radiopharmaceutical
Nuclear & Radiochemistry
MBq
A radioactive compound administered to a patient for diagnosis or treatment.
Relationship between Kp and Kc
Chemical Equilibrium
Dimensionless
The conversion linking the pressure and concentration forms of the equilibrium constant for a gaseous reaction.
Kp = Kc(RT)^Δn
Relative Lowering of Vapour Pressure
Solutions & Colligative Properties
Dimensionless
The fractional reduction in a solvent's vapour pressure caused by dissolving a non-volatile solute.
(p° − p) / p° = x_solute
RNA
Biochemistry & Polymer Chemistry
Dimensionless
A generally single-stranded nucleic acid that carries out the expression of genetic information.
Saturation and Unsaturation
Organic Chemistry
Dimensionless
The distinction between compounds containing only single bonds and those containing multiple bonds or rings.
DoU = (2C + 2 + N − H − X)/2
Schrödinger Wave Equation
Atomic Structure & Periodicity
J
The fundamental equation of quantum mechanics whose solutions give the allowed energies and wavefunctions of a system.
Ĥψ = Eψ
Second-Order Reaction
Chemical Kinetics & Catalysis
L/(mol·s)
A reaction whose rate depends on the square of one concentration or on the product of two concentrations.
1/[A] = 1/[A]₀ + kt
Secondary Valence
Inorganic & Coordination Chemistry
Dimensionless
In Werner's theory, the non-ionisable valence corresponding to the coordination number, satisfied by ligands in fixed spatial positions.
Selectivity
Chemical Kinetics & Catalysis
Dimensionless
The ability of a catalyst to direct a reaction towards one particular product among several possible ones.
selectivity = desired product / total product
SI Base Units
Foundations of Chemistry
Various
The seven defined units of the International System from which every other measurement unit is derived.
Solid State
States of Matter & Gas Laws
Dimensionless
The state of matter in which particles are held in fixed positions, giving a definite shape and volume.
Solubility of Gases
Solutions & Colligative Properties
mol/L
The amount of a gas that dissolves in a given volume of liquid at a stated temperature and partial pressure.
S ∝ p, S decreases with T
Solvent
Solutions & Colligative Properties
L
The component of a solution present in the greater amount, which dissolves and disperses the solute.
Specific Heat Capacity
Thermochemistry & Thermodynamics
J/(kg·K)
The heat required to raise the temperature of one kilogram of a substance by one kelvin.
c = q / (mΔT)
sp³ Hybridisation
Chemical Bonding & Molecular Structure
degrees
The mixing of one s and three p orbitals to give four hybrid orbitals directed towards the corners of a tetrahedron.
4 hybrids, 109.5°
Steric Factor
Chemical Kinetics & Catalysis
Dimensionless
The fraction of sufficiently energetic collisions that also have the correct spatial orientation for reaction.
p = A / Z
Stoichiometric Coefficient
Stoichiometry & Chemical Reactions
Dimensionless
The number written before a formula in a balanced equation, giving the relative amount of that substance consumed or produced.