Results for “Mole”
26 terms · page 1 of 2
Self-Ionisation of Water
Acids, Bases & Salts
mol/L
The reaction in which two water molecules transfer a proton to give a hydronium and a hydroxide ion.
2H₂O ⇌ H₃O⁺ + OH⁻
Semipermeable Membrane
Solutions & Colligative Properties
Dimensionless
A barrier that allows solvent molecules to pass while blocking larger solute particles.
Solution
Solutions & Colligative Properties
Dimensionless
A homogeneous mixture in which one or more substances are dispersed uniformly at the molecular or ionic level in another.
Solvation
Solutions & Colligative Properties
kJ/mol
The surrounding and stabilisation of a solute particle by a shell of solvent molecules.
Standard Enthalpy of Combustion
Thermochemistry & Thermodynamics
kJ/mol
The enthalpy change when one mole of a substance burns completely in excess oxygen under standard conditions.
ΔH_c°
Standard Enthalpy of Formation
Thermochemistry & Thermodynamics
kJ/mol
The enthalpy change when one mole of a compound forms from its elements in their standard states.
ΔH_f°
Standard Molar Entropy
Thermochemistry & Thermodynamics
J/(mol·K)
The absolute entropy of one mole of a substance in its standard state at 298 K.
ΔS° = ΣS°(products) − ΣS°(reactants)
Stereoisomerism
Organic Chemistry
Dimensionless
Isomerism in which molecules have identical connectivity but differ in the spatial arrangement of their atoms.
Stoichiometry
Stoichiometry & Chemical Reactions
mol
The quantitative study of the mass and mole relationships between reactants and products in a chemical reaction.
n_A / a = n_B / b
Structural Formula
Foundations of Chemistry
Dimensionless
A representation showing how the atoms in a molecule are connected and, often, how they are arranged in space.
Substitution Reaction
Stoichiometry & Chemical Reactions
Dimensionless
A reaction in which one atom or group in a molecule is replaced by another.
R–X + Y → R–Y + X
Surface Tension
States of Matter & Gas Laws
N/m
The energy required to increase the surface area of a liquid by unit amount, arising from unbalanced intermolecular forces at the surface.
γ = F / L
Saturation and Unsaturation
Organic Chemistry
Dimensionless
The distinction between compounds containing only single bonds and those containing multiple bonds or rings.
DoU = (2C + 2 + N − H − X)/2
Schrödinger Wave Equation
Atomic Structure & Periodicity
J
The fundamental equation of quantum mechanics whose solutions give the allowed energies and wavefunctions of a system.
Ĥψ = Eψ
Second-Order Reaction
Chemical Kinetics & Catalysis
L/(mol·s)
A reaction whose rate depends on the square of one concentration or on the product of two concentrations.
1/[A] = 1/[A]₀ + kt
Secondary Valence
Inorganic & Coordination Chemistry
Dimensionless
In Werner's theory, the non-ionisable valence corresponding to the coordination number, satisfied by ligands in fixed spatial positions.
Selectivity
Chemical Kinetics & Catalysis
Dimensionless
The ability of a catalyst to direct a reaction towards one particular product among several possible ones.
selectivity = desired product / total product
SI Base Units
Foundations of Chemistry
Various
The seven defined units of the International System from which every other measurement unit is derived.
Solid State
States of Matter & Gas Laws
Dimensionless
The state of matter in which particles are held in fixed positions, giving a definite shape and volume.
Solubility of Gases
Solutions & Colligative Properties
mol/L
The amount of a gas that dissolves in a given volume of liquid at a stated temperature and partial pressure.
S ∝ p, S decreases with T
Solvent
Solutions & Colligative Properties
L
The component of a solution present in the greater amount, which dissolves and disperses the solute.
Specific Heat Capacity
Thermochemistry & Thermodynamics
J/(kg·K)
The heat required to raise the temperature of one kilogram of a substance by one kelvin.
c = q / (mΔT)
sp³ Hybridisation
Chemical Bonding & Molecular Structure
degrees
The mixing of one s and three p orbitals to give four hybrid orbitals directed towards the corners of a tetrahedron.
4 hybrids, 109.5°
Steric Factor
Chemical Kinetics & Catalysis
Dimensionless
The fraction of sufficiently energetic collisions that also have the correct spatial orientation for reaction.
p = A / Z