Terms starting with R
53 terms · page 1 of 3
Racemic Mixture
Organic Chemistry
degrees
An equimolar mixture of two enantiomers, which shows no net optical rotation.
50:50 (+) and (−)
Radiation Dose
Nuclear & Radiochemistry
Gy
A measure of the energy deposited in matter by ionising radiation.
D = E / m
Radioactive Activity
Nuclear & Radiochemistry
Bq
The number of nuclear disintegrations occurring in a sample per unit time.
A = λN
Radioactive Decay Series
Nuclear & Radiochemistry
Dimensionless
A sequence of successive radioactive decays leading from a long-lived parent to a stable end product.
Radioactive Half-Life
Nuclear & Radiochemistry
s
The time required for half the nuclei in a radioactive sample to decay.
t½ = 0.693 / λ
Radioactive Tracer
Nuclear & Radiochemistry
Bq
A radioisotope introduced into a system so that its pathway can be followed by detecting its radiation.
Radioactive Waste
Nuclear & Radiochemistry
Bq/kg
Material containing radionuclides for which no further use is foreseen and which requires controlled disposal.
Radioactivity
Nuclear & Radiochemistry
Bq
The spontaneous emission of particles or electromagnetic radiation from unstable atomic nuclei.
Radiocarbon Dating
Nuclear & Radiochemistry
years
A dating technique that determines the age of organic material from its residual carbon-14 content.
t = (t½ / 0.693) ln(N₀/N)
Radioisotope
Nuclear & Radiochemistry
Dimensionless
An isotope of an element whose nucleus is unstable and undergoes radioactive decay.
Radiolysis
Nuclear & Radiochemistry
Dimensionless
The chemical decomposition of a substance caused by ionising radiation.
H₂O →(radiation) H· + OH·
Radiometric Dating
Nuclear & Radiochemistry
years
The general technique of determining the age of a sample from the decay of a radioactive nuclide it contains.
t = (1/λ) ln(1 + D/P)
Radiopharmaceutical
Nuclear & Radiochemistry
MBq
A radioactive compound administered to a patient for diagnosis or treatment.
Radiotherapy
Nuclear & Radiochemistry
Gy
The medical use of ionising radiation to destroy cancerous tissue.
Raman Spectroscopy
Analytical Chemistry & Spectroscopy
cm⁻¹
A vibrational technique based on the small shift in frequency of light scattered inelastically by molecules.
Δν̃ = ν̃_incident − ν̃_scattered
Random Error
Analytical Chemistry & Spectroscopy
Various
An error that varies unpredictably in size and direction between repeated measurements.
Raoult's Law
Solutions & Colligative Properties
Pa
The partial vapour pressure of each component of an ideal solution equals its mole fraction times its pure vapour pressure.
p_A = x_A p°_A
Rate Constant
Chemical Kinetics & Catalysis
Various
The proportionality constant in a rate law, characteristic of a given reaction at a given temperature.
k = A e^(−Ea/RT)
Rate Law
Chemical Kinetics & Catalysis
mol/(L·s)
An experimentally determined equation expressing reaction rate as a function of reactant concentrations.
rate = k[A]^m[B]^n
Rate-Determining Step
Chemical Kinetics & Catalysis
Dimensionless
The slowest step in a reaction mechanism, which limits the overall rate.
Reactant
Stoichiometry & Chemical Reactions
mol
A starting substance that is consumed during a chemical reaction.
Reaction Intermediate
Chemical Kinetics & Catalysis
mol/L
A species produced in one step of a mechanism and consumed in a later one, so it does not appear in the overall equation.
Reaction Mechanism
Chemical Kinetics & Catalysis
Dimensionless
The detailed sequence of elementary steps by which reactants are converted into products.
Reaction Quotient
Chemical Equilibrium
Various
The same ratio as the equilibrium constant but evaluated with the concentrations actually present at any moment.
Q = [C]^c[D]^d / [A]^a[B]^b