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Terms starting with R

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Organic Chemistry

Racemic Mixture

An equimolar mixture of two enantiomers, which shows no net optical rotation.

50:50 (+) and (−) degrees
Nuclear & Radiochemistry

Radiation Dose

A measure of the energy deposited in matter by ionising radiation.

D = E / m Gy
Nuclear & Radiochemistry

Radioactive Activity

The number of nuclear disintegrations occurring in a sample per unit time.

A = λN Bq
Nuclear & Radiochemistry

Radioactive Decay Series

A sequence of successive radioactive decays leading from a long-lived parent to a stable end product.

Dimensionless
Nuclear & Radiochemistry

Radioactive Half-Life

The time required for half the nuclei in a radioactive sample to decay.

t½ = 0.693 / λ s
Nuclear & Radiochemistry

Radioactive Tracer

A radioisotope introduced into a system so that its pathway can be followed by detecting its radiation.

Bq
Nuclear & Radiochemistry

Radioactive Waste

Material containing radionuclides for which no further use is foreseen and which requires controlled disposal.

Bq/kg
Nuclear & Radiochemistry

Radioactivity

The spontaneous emission of particles or electromagnetic radiation from unstable atomic nuclei.

Bq
Nuclear & Radiochemistry

Radiocarbon Dating

A dating technique that determines the age of organic material from its residual carbon-14 content.

t = (t½ / 0.693) ln(N₀/N) years
Nuclear & Radiochemistry

Radioisotope

An isotope of an element whose nucleus is unstable and undergoes radioactive decay.

Dimensionless
Nuclear & Radiochemistry

Radiolysis

The chemical decomposition of a substance caused by ionising radiation.

H₂O →(radiation) H· + OH· Dimensionless
Nuclear & Radiochemistry

Radiometric Dating

The general technique of determining the age of a sample from the decay of a radioactive nuclide it contains.

t = (1/λ) ln(1 + D/P) years
Nuclear & Radiochemistry

Radiopharmaceutical

A radioactive compound administered to a patient for diagnosis or treatment.

MBq
Nuclear & Radiochemistry

Radiotherapy

The medical use of ionising radiation to destroy cancerous tissue.

Gy
Analytical Chemistry & Spectroscopy

Raman Spectroscopy

A vibrational technique based on the small shift in frequency of light scattered inelastically by molecules.

Δν̃ = ν̃_incident − ν̃_scattered cm⁻¹
Analytical Chemistry & Spectroscopy

Random Error

An error that varies unpredictably in size and direction between repeated measurements.

Various
Solutions & Colligative Properties

Raoult's Law

The partial vapour pressure of each component of an ideal solution equals its mole fraction times its pure vapour pressure.

p_A = x_A p°_A Pa
Chemical Kinetics & Catalysis

Rate Constant

The proportionality constant in a rate law, characteristic of a given reaction at a given temperature.

k = A e^(−Ea/RT) Various
Chemical Kinetics & Catalysis

Rate Law

An experimentally determined equation expressing reaction rate as a function of reactant concentrations.

rate = k[A]^m[B]^n mol/(L·s)
Chemical Kinetics & Catalysis

Rate-Determining Step

The slowest step in a reaction mechanism, which limits the overall rate.

Dimensionless
Stoichiometry & Chemical Reactions

Reactant

A starting substance that is consumed during a chemical reaction.

mol
Chemical Kinetics & Catalysis

Reaction Intermediate

A species produced in one step of a mechanism and consumed in a later one, so it does not appear in the overall equation.

mol/L
Chemical Kinetics & Catalysis

Reaction Mechanism

The detailed sequence of elementary steps by which reactants are converted into products.

Dimensionless
Chemical Equilibrium

Reaction Quotient

The same ratio as the equilibrium constant but evaluated with the concentrations actually present at any moment.

Q = [C]^c[D]^d / [A]^a[B]^b Various