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Centrifugation Foundations of Chemistry g (RCF) A separation technique that uses rapid rotation to generate an effective gravitational field, forcing denser components to the bottom of a tube. RCF = 1.118 × 10⁻⁵ × r × N² Chain Isomerism Organic Chemistry Dimensionless Structural isomerism arising from different arrangements of the carbon skeleton. Chain Reaction Chemical Kinetics & Catalysis Dimensionless A self-sustaining reaction sequence in which a reactive intermediate regenerates itself at each cycle. initiation → propagation → termination Chalcogens Atomic Structure & Periodicity Dimensionless The group 16 elements — oxygen, sulfur, selenium, tellurium and polonium — collectively known as the ore-forming elements. ns² np⁴ Charge Transfer Spectrum Inorganic & Coordination Chemistry nm An intense absorption produced when an electron moves between metal and ligand orbitals. Charles's Law States of Matter & Gas Laws m³/K At constant pressure, the volume of a fixed mass of gas is directly proportional to its absolute temperature. V₁ / T₁ = V₂ / T₂ Chelate Inorganic & Coordination Chemistry Dimensionless A cyclic complex formed when a multidentate ligand grips a metal ion through two or more donor atoms. Chelate Effect Inorganic & Coordination Chemistry kJ/mol The greater stability of a complex containing a multidentate ligand compared with one containing equivalent monodentate ligands. ΔS favourable Chemical Bond Chemical Bonding & Molecular Structure kJ/mol The attractive force that holds atoms or ions together in a stable chemical species. Chemical Change Foundations of Chemistry Dimensionless A change in which the atoms of one or more substances are rearranged into new substances with different properties. Chemical Equation Stoichiometry & Chemical Reactions Dimensionless A symbolic representation of a chemical reaction showing reactants on the left and products on the right. aA + bB → cC + dD Chemical Equilibrium Chemical Equilibrium Dimensionless The state of a reversible reaction in which the forward and reverse reactions proceed at equal rates, so no net change in composition occurs. aA + bB ⇌ cC + dD Chemical Formula Foundations of Chemistry Dimensionless A symbolic notation that states which elements a substance contains and in what proportions, using element symbols and subscripts. Chemical Kinetics Chemical Kinetics & Catalysis mol/(L·s) The study of reaction rates, the factors that influence them, and the step-by-step mechanisms by which reactions occur. Chemical Property Foundations of Chemistry Various A characteristic that describes how a substance transforms into a different substance, observable only during a chemical reaction. Chemical Shift Analytical Chemistry & Spectroscopy ppm The position of an NMR signal relative to a reference, expressed in parts per million of the operating frequency. δ = (ν_sample − ν_ref) × 10⁶ / ν_spectrometer Chemical Symbol Foundations of Chemistry Dimensionless The one-, two- or three-letter abbreviation used internationally to represent an element. Chemisorption Chemical Kinetics & Catalysis kJ/mol Strong adsorption in which actual chemical bonds form between the adsorbate and the surface. ΔH ≈ −80 to −400 kJ/mol Chirality Organic Chemistry Dimensionless The property of a molecule that makes it non-superimposable on its mirror image. Chromatography Analytical Chemistry & Spectroscopy Dimensionless A family of separation techniques that partition components between a stationary and a mobile phase. Chromophore Analytical Chemistry & Spectroscopy nm The part of a molecule responsible for absorbing light at a particular wavelength. Closed System Thermochemistry & Thermodynamics Dimensionless A system that can exchange energy but not matter with its surroundings. Cloud Chamber Nuclear & Radiochemistry Dimensionless A device that reveals the paths of ionising particles as visible trails of condensed vapour. Coagulation Solutions & Colligative Properties Dimensionless The aggregation of colloidal particles into clusters large enough to settle out of the dispersion.