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Foundations of Chemistry

Centrifugation

A separation technique that uses rapid rotation to generate an effective gravitational field, forcing denser components to the bottom of a…

RCF = 1.118 × 10⁻⁵ × r × N² g (RCF)
Organic Chemistry

Chain Isomerism

Structural isomerism arising from different arrangements of the carbon skeleton.

Dimensionless
Chemical Kinetics & Catalysis

Chain Reaction

A self-sustaining reaction sequence in which a reactive intermediate regenerates itself at each cycle.

initiation → propagation → termination Dimensionless
Atomic Structure & Periodicity

Chalcogens

The group 16 elements — oxygen, sulfur, selenium, tellurium and polonium — collectively known as the ore-forming elements.

ns² np⁴ Dimensionless
Inorganic & Coordination Chemistry

Charge Transfer Spectrum

An intense absorption produced when an electron moves between metal and ligand orbitals.

nm
States of Matter & Gas Laws

Charles's Law

At constant pressure, the volume of a fixed mass of gas is directly proportional to its absolute temperature.

V₁ / T₁ = V₂ / T₂ m³/K
Inorganic & Coordination Chemistry

Chelate

A cyclic complex formed when a multidentate ligand grips a metal ion through two or more donor atoms.

Dimensionless
Inorganic & Coordination Chemistry

Chelate Effect

The greater stability of a complex containing a multidentate ligand compared with one containing equivalent monodentate ligands.

ΔS favourable kJ/mol
Chemical Bonding & Molecular Structure

Chemical Bond

The attractive force that holds atoms or ions together in a stable chemical species.

kJ/mol
Foundations of Chemistry

Chemical Change

A change in which the atoms of one or more substances are rearranged into new substances with different properties.

Dimensionless
Stoichiometry & Chemical Reactions

Chemical Equation

A symbolic representation of a chemical reaction showing reactants on the left and products on the right.

aA + bB → cC + dD Dimensionless
Chemical Equilibrium

Chemical Equilibrium

The state of a reversible reaction in which the forward and reverse reactions proceed at equal rates, so no net change in composition…

aA + bB ⇌ cC + dD Dimensionless
Foundations of Chemistry

Chemical Formula

A symbolic notation that states which elements a substance contains and in what proportions, using element symbols and subscripts.

Dimensionless
Chemical Kinetics & Catalysis

Chemical Kinetics

The study of reaction rates, the factors that influence them, and the step-by-step mechanisms by which reactions occur.

mol/(L·s)
Foundations of Chemistry

Chemical Property

A characteristic that describes how a substance transforms into a different substance, observable only during a chemical reaction.

Various
Analytical Chemistry & Spectroscopy

Chemical Shift

The position of an NMR signal relative to a reference, expressed in parts per million of the operating frequency.

δ = (ν_sample − ν_ref) × 10⁶ / ν_spectrometer ppm
Foundations of Chemistry

Chemical Symbol

The one-, two- or three-letter abbreviation used internationally to represent an element.

Dimensionless
Chemical Kinetics & Catalysis

Chemisorption

Strong adsorption in which actual chemical bonds form between the adsorbate and the surface.

ΔH ≈ −80 to −400 kJ/mol kJ/mol
Organic Chemistry

Chirality

The property of a molecule that makes it non-superimposable on its mirror image.

Dimensionless
Analytical Chemistry & Spectroscopy

Chromatography

A family of separation techniques that partition components between a stationary and a mobile phase.

Dimensionless
Analytical Chemistry & Spectroscopy

Chromophore

The part of a molecule responsible for absorbing light at a particular wavelength.

nm
Thermochemistry & Thermodynamics

Closed System

A system that can exchange energy but not matter with its surroundings.

Dimensionless
Nuclear & Radiochemistry

Cloud Chamber

A device that reveals the paths of ionising particles as visible trails of condensed vapour.

Dimensionless
Solutions & Colligative Properties

Coagulation

The aggregation of colloidal particles into clusters large enough to settle out of the dispersion.

Dimensionless