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Organic Chemistry

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Cannizzaro Reaction Organic Chemistry Dimensionless The disproportionation of an aldehyde with no alpha hydrogen under concentrated alkali into an alcohol and a carboxylate. 2RCHO + OH⁻ → RCH₂OH + RCOO⁻ Carbanion Organic Chemistry Dimensionless An organic ion in which a carbon atom bears a negative charge and a lone pair. R₃C⁻ Carbocation Organic Chemistry Dimensionless An organic ion in which a carbon atom bears a positive charge and only six valence electrons. R₃C⁺ Carboxylic Acid Organic Chemistry Dimensionless A compound containing a carboxyl group, in which a carbonyl and a hydroxyl group share the same carbon. R–COOH Chain Isomerism Organic Chemistry Dimensionless Structural isomerism arising from different arrangements of the carbon skeleton. Chirality Organic Chemistry Dimensionless The property of a molecule that makes it non-superimposable on its mirror image. Conformational Isomerism Organic Chemistry kJ/mol The different spatial arrangements a molecule can adopt through rotation about single bonds.