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Analytical Chemistry & Spectroscopy

Ultraviolet–Visible Spectroscopy

A technique that measures the absorption of ultraviolet and visible light by electronic transitions within molecules.

Formula / equation A = log(I₀/I)
Unit nm

In depth

Absorption promotes electrons between molecular orbitals, typically pi to pi star or n to pi star. The wavelength of maximum absorption indicates the extent of conjugation, while the absorbance gives concentration through the Beer–Lambert law.

Examples in the real world

Quantifying DNA at 260 nm; following an enzyme reaction by the appearance of a coloured product.