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Chemical Bonding & Molecular Structure

Trigonal Planar Geometry

A flat molecular shape with three bonded atoms arranged around a central atom at 120°.

Formula / equation AX₃
Unit degrees

In depth

Three electron domains with no lone pairs give this arrangement, matching sp² hybridisation. The unhybridised p orbital perpendicular to the plane is available for pi bonding or, in electron-deficient species such as BF₃, remains empty and makes the molecule a Lewis acid.

Examples in the real world

BF₃, the carbonate ion CO₃²⁻, and the sp² carbons of ethene and formaldehyde.