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Atomic Structure & Periodicity

Spin Quantum Number

The quantum number mₛ describing the intrinsic angular momentum of an electron, restricted to +½ or −½.

Formula / equation mₛ = ±½
Unit Dimensionless

In depth

Electron spin is a purely quantum property with no classical analogue, first demonstrated by the Stern–Gerlach experiment. Because only two spin states exist, an orbital can hold at most two electrons. Unpaired spins give rise to paramagnetism and to the signals detected in EPR and NMR spectroscopy.

Examples in the real world

Helium's two 1s electrons occupy the same orbital with opposite spins, written 1s².