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Atomic Structure & Periodicity

d-Block Elements

The elements of groups 3 to 12, whose valence electrons fill d orbitals of the penultimate shell.

Formula / equation (n−1)d¹⁻¹⁰ ns⁰⁻²
Unit Dimensionless

In depth

Partly filled d orbitals give these metals variable oxidation states, coloured compounds, paramagnetism, catalytic activity and a strong tendency to form complex ions. High melting points and densities follow from strong metallic bonding involving both s and d electrons.

Examples in the real world

Iron in +2 and +3 states, chromium's series of coloured oxidation states, and vanadium pentoxide as a contact-process catalyst.