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Acids, Bases & Salts

pKb

The negative logarithm of the base dissociation constant.

Formula / equation pKb = −log Kb
Unit Dimensionless

In depth

A lower pKb indicates a stronger base. Because pKa and pKb of a conjugate pair always sum to 14 in water at 25 °C, modern practice increasingly quotes only the pKa of the conjugate acid, which conveys exactly the same information on a single scale.

Examples in the real world

Ammonia has pKb 4.75, corresponding to a pKa of 9.25 for the ammonium ion.