Home Wikituition Browse all terms Categories
Random term
Organic Chemistry

Optical Isomerism

Stereoisomerism in which molecules are non-superimposable mirror images and rotate plane-polarised light in opposite directions.

Unit degrees

In depth

Optical isomers share every scalar physical property — melting point, density, solubility — and differ only in their interaction with other chiral entities. Since biological receptors are chiral, the two forms of a drug can have utterly different effects.

Examples in the real world

The two forms of limonene smelling of orange and of lemon; thalidomide's tragically different enantiomers.