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Stoichiometry & Chemical Reactions

Elimination Reaction

A reaction in which two substituents are removed from adjacent atoms, generating a multiple bond.

Formula / equation R–CH₂–CHX–R → R–CH=CH–R + HX
Unit Dimensionless

In depth

Elimination is the reverse of addition and typically needs a strong base or high temperature. It competes directly with substitution, with bulky bases, high temperature and hindered substrates all favouring elimination. Zaitsev's rule predicts that the more substituted alkene usually predominates.

Examples in the real world

Heating 2-bromobutane with alcoholic KOH gives but-2-ene as the major product.