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Organic Chemistry

E2 Reaction

A single-step elimination in which a base removes a proton as the leaving group departs, forming a double bond.

Formula / equation rate = k[substrate][base]
Unit L/(mol·s)

In depth

The reaction is concerted and requires the hydrogen and leaving group to be anti-periplanar, which makes the stereochemistry of the product predictable. Strong bulky bases and high temperature favour E2 over the competing SN2 pathway.

Examples in the real world

2-bromobutane with hot ethanolic potassium hydroxide giving but-2-ene as the major product.