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Analytical Chemistry & Spectroscopy

Carbon-13 NMR

An NMR technique that detects the carbon-13 nucleus to reveal the carbon skeleton of a molecule.

Formula / equation δ 0–220 ppm
Unit ppm

In depth

Only 1.1% of natural carbon is the magnetically active isotope, so the signals are weak and require many scans. Spectra are usually proton-decoupled, giving one sharp singlet per distinct carbon environment, which makes counting inequivalent carbons straightforward.

Examples in the real world

A carbonyl carbon appearing near 200 ppm; aromatic carbons clustering between 120 and 150 ppm.