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States of Matter & Gas Laws

Critical Temperature

The temperature above which a gas cannot be liquefied by pressure alone, however great.

T_c = 8a / 27Rb K
Biochemistry & Polymer Chemistry

Cross-Linking

The formation of covalent bonds between separate polymer chains.

Dimensionless
Solutions & Colligative Properties

Cryoscopic Constant

The freezing point depression produced by a one-molal solution of a non-electrolyte in a given solvent.

K_f = RT_f²M / ΔH_fus K·kg/mol
States of Matter & Gas Laws

Crystal Defect

Any irregularity that interrupts the perfectly ordered arrangement of particles in a crystal.

Dimensionless
Inorganic & Coordination Chemistry

Crystal Field Splitting Energy

The energy difference between the sets of d orbitals produced when a ligand field lifts their degeneracy.

Δ₀ or Δ_t cm⁻¹
Inorganic & Coordination Chemistry

Crystal Field Stabilisation Energy

The net energy gained by a complex through the preferential occupation of lower-energy d orbitals.

CFSE = (−0.4n_t2g + 0.6n_eg)Δ₀ kJ/mol
Inorganic & Coordination Chemistry

Crystal Field Theory

The model treating metal–ligand bonding as purely electrostatic and analysing how ligand fields split the metal d orbitals.

kJ/mol
Chemical Bonding & Molecular Structure

Crystal Lattice

The regular, repeating three-dimensional arrangement of particles in a crystalline solid.

Dimensionless
States of Matter & Gas Laws

Crystalline Solid

A solid in which the constituent particles are arranged in a regular, repeating three-dimensional pattern extending over long distances.

Dimensionless
Foundations of Chemistry

Crystallisation

A purification technique in which a solid is separated from solution as an ordered crystalline lattice.

Dimensionless
Nuclear & Radiochemistry

Curie

The older unit of radioactivity, defined as the activity of one gram of radium-226.

1 Ci = 3.7 × 10¹⁰ Bq Ci
Thermochemistry & Thermodynamics

Cyclic Process

A process in which a system undergoes a series of changes and returns to its exact initial state.

ΔU = 0, q = −w J
Atomic Structure & Periodicity

d-Block Elements

The elements of groups 3 to 12, whose valence electrons fill d orbitals of the penultimate shell.

(n−1)d¹⁻¹⁰ ns⁰⁻² Dimensionless
Foundations of Chemistry

Dalton's Atomic Theory

The 1808 model proposing that elements consist of indivisible atoms that are identical within an element and combine in fixed whole-number…

Dimensionless
States of Matter & Gas Laws

Dalton's Law of Partial Pressures

The total pressure of a gas mixture equals the sum of the pressures each component would exert alone in the same volume.

p_total = p₁ + p₂ + p₃ … Pa
Electrochemistry & Redox

Daniell Cell

The classic galvanic cell consisting of a zinc electrode in zinc sulfate and a copper electrode in copper sulfate.

Zn + Cu²⁺ → Zn²⁺ + Cu, E° = 1.10 V V
Atomic Structure & Periodicity

de Broglie Relation

The relation stating that every particle has an associated wavelength inversely proportional to its momentum.

λ = h / mv m
Chemical Equilibrium

Debye–Hückel Limiting Law

The theoretical relation predicting activity coefficients of ions in very dilute solution from their charge and the ionic strength.

log γ = −A z² √I Dimensionless
Foundations of Chemistry

Decantation

The separation of a liquid from a settled solid or a denser immiscible liquid by carefully pouring off the upper layer.

Dimensionless
Nuclear & Radiochemistry

Decay Constant

The probability per unit time that a given nucleus will decay.

λ = 0.693 / t½ s⁻¹
Electrochemistry & Redox

Decomposition Potential

The minimum voltage that must be applied to an electrolytic cell before continuous electrolysis begins.

V
Stoichiometry & Chemical Reactions

Decomposition Reaction

A reaction in which a single compound breaks down into two or more simpler substances.

AB → A + B Dimensionless
Atomic Structure & Periodicity

Degenerate Orbitals

Two or more orbitals in the same atom that have exactly the same energy.

Dimensionless
Chemical Equilibrium

Degree of Dissociation

The fraction of the original substance that has broken apart at equilibrium.

α = amount dissociated / initial amount Dimensionless