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Esterification Stoichiometry & Chemical Reactions Dimensionless The acid-catalysed condensation of a carboxylic acid with an alcohol to form an ester and water. RCOOH + R′OH ⇌ RCOOR′ + H₂O Ether Organic Chemistry Dimensionless A compound in which an oxygen atom is bonded to two carbon atoms. R–O–R′ Evaporation States of Matter & Gas Laws kJ/mol The escape of molecules from the surface of a liquid into the vapour phase below the boiling point. Excess Reagent Stoichiometry & Chemical Reactions mol A reactant present in a greater amount than is needed to consume the limiting reagent completely. n_excess = n_initial − n_reacted Exergonic Reaction Thermochemistry & Thermodynamics kJ/mol A reaction with a negative Gibbs free energy change, which therefore releases usable energy and proceeds spontaneously. ΔG < 0 Exothermic Reaction Stoichiometry & Chemical Reactions kJ/mol A reaction that releases energy to the surroundings, giving a negative enthalpy change. ΔH < 0 Expanded Octet Chemical Bonding & Molecular Structure Dimensionless A bonding arrangement in which a central atom is surrounded by more than eight valence electrons. Extensive Property Foundations of Chemistry Various A property whose value is directly proportional to the quantity of matter in the sample. Extent of Reaction Chemical Equilibrium mol A single variable measuring how far a reaction has progressed from pure reactants towards products. ξ = (n_i − n_i°) / ν_i