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Organic Chemistry

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Organic Chemistry

Organic Chemistry

The study of the structure, properties, composition and reactions of carbon-containing compounds.

Dimensionless
Organic Chemistry

Oxidation of Alcohols

The conversion of alcohols to carbonyl compounds or carboxylic acids by removal of hydrogen.

R–CH₂OH → RCHO → RCOOH Dimensionless
Organic Chemistry

Phenol

A compound in which a hydroxyl group is bonded directly to an aromatic ring.

C₆H₅–OH Dimensionless
Organic Chemistry

Position Isomerism

Structural isomerism arising from a functional group occupying different positions on the same carbon skeleton.

Dimensionless
Organic Chemistry

Racemic Mixture

An equimolar mixture of two enantiomers, which shows no net optical rotation.

50:50 (+) and (−) degrees
Organic Chemistry

Resonance Effect

The delocalisation of pi or lone pair electrons through a conjugated system, altering electron density at distant atoms.

−M and +M effects Dimensionless
Organic Chemistry

Saturation and Unsaturation

The distinction between compounds containing only single bonds and those containing multiple bonds or rings.

DoU = (2C + 2 + N − H − X)/2 Dimensionless
Organic Chemistry

SN1 Reaction

A two-step nucleophilic substitution proceeding through a carbocation intermediate.

rate = k[substrate] s⁻¹
Organic Chemistry

SN2 Reaction

A single-step nucleophilic substitution in which bond formation and bond breaking occur simultaneously.

rate = k[substrate][nucleophile] L/(mol·s)
Organic Chemistry

Stereoisomerism

Isomerism in which molecules have identical connectivity but differ in the spatial arrangement of their atoms.

Dimensionless
Organic Chemistry

Structural Isomerism

Isomerism in which the compounds differ in the order in which their atoms are connected.

Dimensionless
Organic Chemistry

Zaitsev's Rule

In an elimination reaction, the major product is usually the more highly substituted and therefore more stable alkene.

Dimensionless