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Electrochemistry & Redox

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Electrochemistry & Redox

Redox Couple

The oxidised and reduced forms of the same species, considered together as a conjugate pair.

Ox / Red V
Electrochemistry & Redox

Reducing Agent

A species that donates electrons to another substance and is itself oxidised in the process.

V
Electrochemistry & Redox

Reduction

The gain of electrons by a species, accompanied by a decrease in its oxidation number.

Xⁿ⁺ + n e⁻ → X Dimensionless
Electrochemistry & Redox

Reference Electrode

A half-cell with a stable, known and reproducible potential, used as a fixed point against which other potentials are measured.

V
Electrochemistry & Redox

Rusting

The corrosion of iron in the presence of both oxygen and water to form hydrated iron(III) oxide.

4Fe + 3O₂ + 2xH₂O → 2Fe₂O₃·xH₂O Dimensionless
Electrochemistry & Redox

Sacrificial Anode

A block of reactive metal attached to a structure so that it corrodes preferentially and protects the structure.

Dimensionless
Electrochemistry & Redox

Salt Bridge

A conducting connection between the two half-cells of a galvanic cell that completes the circuit and maintains electrical neutrality.

Dimensionless
Electrochemistry & Redox

Secondary Cell

A cell whose reaction can be reversed by an applied current, allowing it to be recharged and reused.

V
Electrochemistry & Redox

Selective Discharge

The preferential reaction of one ion over others at an electrode during electrolysis.

V
Electrochemistry & Redox

Standard Electrode Potential

The potential of a half-cell measured against the standard hydrogen electrode under standard conditions.

E° at 298 K, 1 M, 1 bar V
Electrochemistry & Redox

Standard Hydrogen Electrode

The reference half-cell, consisting of hydrogen gas at 1 bar bubbled over platinum in 1 M acid, assigned a potential of exactly zero.

2H⁺ + 2e⁻ ⇌ H₂, E° = 0.00 V V
Electrochemistry & Redox

Transport Number

The fraction of the total current carried by a particular ion in an electrolyte solution.

t₊ = λ₊ / (λ₊ + λ₋) Dimensionless