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Electrochemistry & Redox

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Electrochemistry & Redox

Electrorefining

The purification of a metal by dissolving it from an impure anode and depositing it in pure form at the cathode.

Dimensionless
Electrochemistry & Redox

Electrowinning

The extraction of a metal from a solution or molten salt of its ore by electrolysis.

kWh/kg
Electrochemistry & Redox

Faraday Constant

The electric charge carried by one mole of electrons.

F = 96,485 C/mol C/mol
Electrochemistry & Redox

Faraday's First Law of Electrolysis

The mass of a substance liberated at an electrode is directly proportional to the quantity of electricity passed.

m = Z I t g
Electrochemistry & Redox

Faraday's Second Law of Electrolysis

When the same quantity of electricity passes through different electrolytes, the masses deposited are proportional to their chemical…

m₁/m₂ = E₁/E₂ g
Electrochemistry & Redox

Free Energy and Cell Potential

The relation linking the Gibbs energy change of a cell reaction to the electromotive force it generates.

ΔG = −nFE kJ/mol
Electrochemistry & Redox

Fuel Cell

An electrochemical cell that generates electricity continuously from a fuel and oxidant supplied from outside.

V
Electrochemistry & Redox

Galvanic Cell

An electrochemical cell in which a spontaneous redox reaction generates electrical energy.

E°cell > 0 V
Electrochemistry & Redox

Galvanic Corrosion

Accelerated corrosion of the more reactive of two different metals in electrical contact within an electrolyte.

mm/year
Electrochemistry & Redox

Galvanisation

The coating of iron or steel with a layer of zinc to protect it from corrosion.

μm
Electrochemistry & Redox

Glass Electrode

An ion-selective electrode whose thin glass membrane develops a potential proportional to the pH of the solution.

E = constant − 0.0592 pH V
Electrochemistry & Redox

Half-Reaction

An equation showing either the oxidation or the reduction part of a redox process, including the electrons transferred.

Ox + n e⁻ ⇌ Red Dimensionless
Electrochemistry & Redox

Hydrogen–Oxygen Fuel Cell

A fuel cell in which hydrogen is oxidised at the anode and oxygen reduced at the cathode, producing only water.

2H₂ + O₂ → 2H₂O, E° = 1.23 V V
Electrochemistry & Redox

Kohlrausch's Law

At infinite dilution, the molar conductivity of an electrolyte is the sum of independent contributions from its cations and anions.

Λ°m = ν₊λ°₊ + ν₋λ°₋ S·cm²/mol
Electrochemistry & Redox

Lead–Acid Accumulator

A rechargeable cell using lead and lead dioxide electrodes in sulfuric acid.

Pb + PbO₂ + 2H₂SO₄ ⇌ 2PbSO₄ + 2H₂O V
Electrochemistry & Redox

Limiting Molar Conductivity

The molar conductivity of an electrolyte extrapolated to infinite dilution, where ionic interactions vanish.

Λ°m S·cm²/mol
Electrochemistry & Redox

Lithium-Ion Battery

A rechargeable cell in which lithium ions shuttle between a graphite anode and a metal oxide cathode.

LiCoO₂ + C₆ ⇌ Li₁₋ₓCoO₂ + LiₓC₆ V
Electrochemistry & Redox

Molar Conductivity

The conductivity of a solution divided by the molar concentration of the electrolyte.

Λm = κ / c S·cm²/mol
Electrochemistry & Redox

Nernst Equation

The equation relating a cell's potential to the concentrations of the species involved.

E = E° − (RT/nF) ln Q V
Electrochemistry & Redox

Overpotential

The extra voltage beyond the theoretical value that must be applied before an electrode reaction proceeds at a useful rate.

η = E_applied − E_equilibrium V
Electrochemistry & Redox

Oxidation

The loss of electrons by a species, accompanied by an increase in its oxidation number.

M → Mⁿ⁺ + n e⁻ Dimensionless
Electrochemistry & Redox

Oxidation Number

The hypothetical charge an atom would carry if all its bonds were treated as fully ionic.

Σ oxidation numbers = overall charge Dimensionless
Electrochemistry & Redox

Oxidising Agent

A species that accepts electrons from another substance and is itself reduced in the process.

V
Electrochemistry & Redox

Primary Cell

A cell in which the electrode reaction is irreversible, so it cannot be recharged.

V