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Thermodynamics & Statistical Physics

Chemical Potential

The change in system free energy per added particle at constant temperature and pressure.

Governing formula μ = (∂G / ∂N)_{T,P} = (∂U / ∂N)_{S,V}
SI unit J/particle (or J/mol)

In depth

Chemical potential governs particle flow: particles diffuse spontaneously from regions of higher chemical potential to lower chemical potential until $μ$ is uniform.

Examples in the real world

Osmotic pressure across semi-permeable cell membranes or phase equilibrium between liquid water and water vapor.