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Chemical Bonding & Molecular Structure

sp² Hybridisation

The mixing of one s and two p orbitals to give three hybrid orbitals in a plane at 120° to each other.

Formula / equation 3 hybrids, 120°
Unit degrees

In depth

One p orbital remains unhybridised and perpendicular to the plane, available for pi bonding. This arrangement produces the trigonal planar geometry of alkenes, carbonyl compounds and aromatic rings, and the parallel p orbitals it leaves behind are what allow pi electrons to delocalise across conjugated systems.

Examples in the real world

Ethene, benzene, the boron in BF₃, and the carbonyl carbon of a ketone.