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Acids, Bases & Salts

Polyprotic Acid

An acid capable of donating more than one proton per molecule.

Formula / equation H₂A ⇌ H⁺ + HA⁻ ⇌ 2H⁺ + A²⁻
Unit mol/L

In depth

Each proton is lost in a separate step with its own dissociation constant, and each successive constant is smaller — typically by four to five orders of magnitude — because removing a proton from an increasingly negative species is progressively harder.

Examples in the real world

Sulfuric acid, carbonic acid, and phosphoric acid, whose three pKa values are 2.1, 7.2 and 12.3.