Home Wikituition Browse all terms Categories
Random term
Inorganic & Coordination Chemistry

Monodentate Ligand

A ligand that binds to the central metal through a single donor atom.

Unit Dimensionless

In depth

Monodentate ligands occupy one coordination site each, so an octahedral complex requires six of them. They are more easily displaced than multidentate ligands because losing one ligand at a time is entropically far less costly than losing a chelate.

Examples in the real world

Water, ammonia, chloride, cyanide and thiocyanate bound through a single atom.